NDRL Radiation Chemistry Data Center Recent Papers in Radiation and Photochemistry 10/08/02 # 02_12

Kinetics	Optical Spectra	Thermodynamics
ESR Studies	Excited States	Photochemistry
Radiation Chemistry	Related Experimental Studies	Multiphase Systems
Polymers	Biological and Medical Aspects	Solar Energy
Industrial and Environmental Applications	Theoretical Studies	Reviews

Kinetics

Measurements of conversion rates of CO to CO₂ in ultraviolet-induced reaction of amorphous D₂O(H₂O)/CO amorphouse ice.
Watanabe, N., Kouchi, A., Astrophys. J. 567(1): 651-5 (2002).

Metal ions affect on the photodynamic actions of cyclodextrin-modified hypocrellin.
Ou, Z.Z., Chen, J.R., Wang, X.S., Zhang, B.W., Cao, Y., Chem. Lett. (2): 206-7 (2002).

Synthesis, characterization, and preliminary intramolecular energy transfer studies of rigid, emissive, rhenium-linked porphyrin dimers.
Splan, K.E., Keefe, M.H., Massari, A.M., Walters, K.A., Hupp, J.T., Inorg. Chem. 41(4): 619-21 (2002).

Photochemistry and photophysics of Cr(III) macrocyclic complexes.
Irwin, G., Kirk, A.D., Mackay, I., Nera, J., Inorg. Chem. 41(4): 874-83 (2002).

Termination rate coefficient of dimethyl itaconate: Comparison of modeling and experimental results.
Vana, P., Yee, L.H., Barner-Kowollik, C., Heuts, J.P.A., Davis, T.P., Macromolecules 35(5): 1651-7 (2002).

Differential anti-lipid peroxidative activity of melatonin.
Kawanishi, S., Sakurai, H., Naturwissenschaften 89(1): 31-3 (2002).

Spectral manifestations of nonplanarity effects in Pd complexes of porphyrins.
Knyukshto, V.N., Shulga, A.M., Sagun, E.I., Zenkevich, E.I., Opt. Spectrosc. (Transl. of Opt. Spektrosk.) 92(1): 53-62 (2002).

Femtosecond study of self-trapped vibrational excitons in crystalline acetanilide - art. no. 067403.
Edler, J., Hamm, P., Scott, A.C., Phys. Rev. Lett. 88(06): 067403 (2002).

Optical Spectra

Matrix infrared spectroscopic studies of the photo-dissociation at 266 nm of ClNO₂ and of ClONO.
Coanga, J.M., Schriver-Mazzuoli, L., Schriver, A., Dahoo, P.R., Chem. Phys. 276(3): 309-20 (2002).

Intrachain annihilation and spatial extension of electronic excitations in a ladder-type conjugated polymer probed via hole-burning.
Romanovskii, Y.V., Bassler, H., Scherf, U., Chem. Phys. 276(3): 321-31 (2002).

Evidence of pronounced electronic coupling in a directly bonded fullerene-ferrocene dyad.
Hauke, F., Hirsch, A., Liu, S.G., Echegoyen, L., Swartz, A., Luo, C.P., Guldi, D.M., ChemPhysChem 3(2): 195-205 (2002).

On the structural stability of montmorillonite submitted to heavy [gamma]-irradiation.
Negron, A., Ramos, S., Blumenfeld, A.L., Pacheco, G., Fripiat, J.J., Clays Clay Miner. 50(1): 35-7 (2002).

A luminescent heterometallic dirhodium-silver chain.
Heyduk, A.F., Krodel, D.J., Meyer, E.E., Nocera, D.G., Inorg. Chem. 41(4): 634-6 (2002).

Control of charge-transfer-induced spin transition temperature on cobalt-iron Prussian blue analogues.
Shimamoto, N., Ohkoshi, S., Sato, O., Hashimoto, K., Inorg. Chem. 41(4): 678-84 (2002).

Photochemistry

Si:2p site-specific excitation and fragmentation of bridged trihalosilyl-trimethylsilyl molecules: role of the bridge and final-state effect.
Nagaoka, S., Fujibuchi, T., Ohshita, J., Nagashima, U., Koyano, I., Chem. Phys. 276(3): 243-56 (2002).

Multiphoton ionization and ab initio calculation studies of pyridazine-(water)_n clusters.
Zhang, B.L., Cai, Y., Mu, X.L., Lou, N.Q., Wang, X.Y., Chem. Phys. 276(3): 277-92 (2002).

Oxidative addition of phosphine-tethered thiols to iron carbonyl: Binuclear phosphinothiolate complexes, ([mu]-SCH₂CH₂PPh₂)₂Fe₂(CO)₄, and hydride derivatives.
Zhao, X., Hsiao, Y.M., Lai, C.H., Reibenspies, J.H., Darensbourg, M.Y., Inorg. Chem. 41(4): 699-708 (2002).

Photochemical transformations of chromophoric methacrylates under the influence of light and laser radiation.
Kucharski, S., Janik, R., Hodge, P., West, D., Khand, K., J. Mater. Chem. 12(3): 449-54 (2002).

Photochromic dihetarylethenes. 12. Synthesis of 5-alkyl-2-(1,3,4-oxadiazol-2-yl)thiophenes and their photochron-derivatives.
Krayushkin, M.M., Stoyanovich, F.M., Zolotarskaya, O.Y., Chernoburova, E.I., Makhova, N.N., Yarovenko, V.N., Zavarzin, I.V., Martynkin, A.Y., Uzhinov, B.M., Khim. Geterotsikl. Soedin. (2): 185-96 (2002).

Reactions of the dinuclear ruthenium complex {([eta]⁵-C₅H₃)₂(SiMe₂)₂}Ru₂(CO)₄, featuring a doubly linked dicyclopentadienyl ligand.
Ovchinnikov, M.V., Klein, D.P., Guzei, I.A., Choi, M.G., Angelici, R.J., Organometallics 21(4): 617-27 (2002).

Reactions of silylenes with acetylenes and 1,3-diacetylenes linked by C-C multiple-bond units.
Ostendorf, D., Saak, W., Weidenbruch, M., Marsmann, H., Organometallics 21(4): 636-40 (2002).

Photosubstitution of (fulvalene)tetracarbonyldiruthenium by alkenes and alkynes: First observation of alkyne coupling on fulvalene dimetals and synthesis of a (fulvalene)dimetallacyclopentadiene(alkene) complex.
Chen, M.C., Eichberg, M.J., Vollhardt, K.P.C., Sercheli, R., Wasser, I.M., Whitener, G.D., Organometallics 21(4): 749-60 (2002).

High pressure photoinduced ring opening of benzene - art. no. 085505.
Ciabini, L., Santoro, M., Bini, R., Schettino, V., Phys. Rev. Lett. 88(08): 085505 (2002).

Asymmetric photodeconjugation: Highly stereoselective synthesis of [alpha]-fluorocarboxylic derivatives.
Bargiggia, F., Dos Santos, S., Piva, O., Synthesis (3): 427-37 (2002).

Geometric requirements for the photolysis of aryloxiranes and cyclic carbonate esters.
Linder, S., White, K., Palmer, M., Arney, B., White, R., Tetrahedron Lett. 43(7): 1169-70 (2002).

Radiation Chemistry

Effect of electric field on the morphology of silver nanocrystals prepared by [gamma]-irradiation.
Wang, F., Ni, Y.H., Ge, X.W., Zhang, Z.C., Chem. Lett. (2): 196-7 (2002).

Experimental Studies

Structures of small gold cluster cations (Au_n⁺, n<14): Ion mobility measurements versus density functional calculations.
Gilb, S., Weis, P., Furche, F., Ahlrichs, R., Kappes, M.M., J. Chem. Phys. 116(10): 4094-101 (2002).

Radical oxygenations with inorganic radicals: can hydroxyl radicals (HO^•) act as donors of oxygen atoms?
Wille, U., Tetrahedron Lett. 43(7): 1239-42 (2002).

Multiphase Systems

A novel one step synthesis of trans-1,4,6,9-tetraazabicyclo[4.4.0]decane over TiO₂/zeolite composite photocatalysts.
Rao, K.V.S., Srinivas, B., Prasad, A.R., Subrahmanyam, M., Chem. Lett. (2): 236-7 (2002).

One-pot monomer self-assembly route to PbS/poly(methyl methacrylate) core/shell nanocomposite thin coatings.
Qiao, Z.P., Xie, G., Huang, J.M., Zhao, S.Y., Chen, X.M., J. Mater. Chem. 12(3): 611-3 (2002).

Effects of crystal structure, size, shape and surface structural differences on photo-induced electron transport in TiO₂ mesoporous electrodes.
Kambe, S., Nakade, S., Wada, Y., Kitamura, T., Yanagida, S., J. Mater. Chem. 12(3): 723-8 (2002).

Self-assembled thin solid films of dioctadecyldimethylammonium cinnamate lamella units that control the photostationary state of E-Z photoisomerizations.
Ohtani, O., Sasai, R., Adachi, T., Hatta, I., Takagi, K., Langmuir 18(4): 1165-70 (2002).

Photochemical functionalization of diamond films.
Strother, T., Knickerbocker, T., Russell, J.N., Butler, J.E., Smith, L.M., Hamers, R.J., Langmuir 18(4): 968-71 (2002).

Preliminary in situ X-ray diffraction measurements of UV-induced photomechanical effects in a mesogenic material.
Sebastiao, P.J., Corsellis, E., Heinrich, B., Guillon, D., Liq. Cryst. 29(3): 479-82 (2002).

Water-in-oil microemulsions as microreactors to control the regioselectivity in the photocycloaddition of 9-substituted anthracenes.
Wu, D.Y., Zhang, L.P., Wu, L.Z., Wang, B.J., Tung, C.H., Tetrahedron Lett. 43(7): 1281-3 (2002).

Photo-induced electron transfer from a dithieno thiophene-based polymer to TiO₂.
Luzzati, S., Basso, M., Catellani, M., Brabec, C.J., Gebeyehu, D., Sariciftci, N.S., Thin Solid Films 403: 52-6 (2002).

Polymers

Effect of environmental temperature on chemical structure and properties of ultraviolet irradiated HDPE.
Wu, S.S., Huaxue Xuebao 60(2): 382-4 (2002).

Plasma polymerization of allylpentafluorobenzene on copper surfaces.
Yang, G.H., Zhang, Y., Kang, E.T., Neoh, K.G., Huan, A.C.H., Lai, D.M.Y., J. Mater. Chem. 12(3): 426-31 (2002).

Photo-sensitivity of recycled photo-degraded polystyrene.
Stevenson, W., White, J.R., J. Mater. Sci. 37(6): 1091-100 (2002).

Photoinitiated polymerization of styrene from self-assembled monolayers on gold.
Schmidt, R., Zhao, T.F., Green, J.B., Dyer, A.J., Langmuir 18(4): 1281-7 (2002).

Control of the radical polymerization of tert-butyl methacrylate in water by a novel combination of sodium nitrite and iron(II) sulfate.
Detrembleur, C., Teyssie, P., Jerome, R., Macromolecules 35(5): 1611-21 (2002).

Photomediated solid-state cross-linking of an elastin-mimetic recombinant protein polymer.
Nagapudi, K., Brinkman, W.T., Leisen, J.E., Huang, L., McMillan, R.A., Apkarian, R.P., Conticello, V.P., Chaikof, E.L., Macromolecules 35(5): 1730-7 (2002).

UV-induced gelation on nanometer scale using liposome reactor.
Kazakov, S., Kaholek, M., Teraoka, I., Levon, K., Macromolecules 35(5): 1911-20 (2002).

Metal salt complexation of spin-coated ultrathin diazosulfonate terpolymer films.
Loppacher, C., Trogisch, S., Braun, F., Zherebov, A., Grafstrom, S., Eng, L.M., Voit, B., Macromolecules 35(5): 1936-40 (2002).

Photoalignment of poly(di-n-hexylsilane) by azobenzene monolayer. 2. Structural optimization of the surface azobenzene monolayer.
Fukuda, K., Seki, T., Ichimura, K., Macromolecules 35(5): 1951-7 (2002).

Synthesis and photopolymerization of hyperbranched polyurethane acrylates applied to UV curable flame retardant coatings.
Zhu, S.W., Shi, W.F., Polym. Int. 51(3): 223-7 (2002).

Liquid crystalline (cyanoethylpropyl)cellulose and its optically anisotropic composites with acrylic polymers.
Okrasa, L., Ulanski, J., Boiteux, G., Polymer 43(8): 2417-24 (2002).

Photoinitiated cationic polymerization using a novel phenacyl anilinium salt.
Kasapoglu, F., Onen, A., Bicak, N., Yagci, Y., Polymer 43(8): 2575-9 (2002).

Solar Energy

Dithienothiophene and dithienothiophene-S,S-dioxide copolymers for photovoltaics.
Catellani, M., Boselli, B., Luzzati, S., Tripodi, C., Thin Solid Films 403: 66-70 (2002).

Industrial and Environmental Applications

Deuterium and fluorine radical reaction kinetics on photoresist.
Greer, F., Coburn, J.W., Graves, D.B., J. Vac. Sci. Technol., B 20(1): 145-53 (2002).

Spectroscopic characterization of acid generation and concentration and free volume evolution in chemically amplified resists.
Jessop, J.L.P., Goldie, S.N., Scranton, A.B., Blanchard, G.J., J. Vac. Sci. Technol., B 20(1): 219-25 (2002).

Preparation of the US semiconductor nanofibril by UV irradiation.
Wu, S.D., Zhu, Z.G., Zhang, Z.P., Zhang, L., Mater. Sci. Eng., B 90(1-2): 206-8 (2002).

Theoretical Studies

Atmospheric formation of OH radicals and H₂O₂ from alkene ozonolysis under humid conditions.
Anglada, J.M., Aplincourt, P., Bofill, J.M., Cremer, D., ChemPhysChem 3(2): 215-21 (2002).

Quantum chemistry calculation research on hypomycin B's intramolecular proton transfer on ground state.
Chen, D.Z., Kong, D.X., Zhang, H.Y., Huaxue Xuebao 60(2): 234-40 (2002).

Coherent control of femtosecond energy localization in nanosystems - art. no. 067402.
Stockman, M.I., Faleev, S.V., Bergman, D.J., Phys. Rev. Lett. 88(06): 067402 (2002).

First-principles theory of the EPR g tensor in solids: Defects in quartz - art. no. 086403.
Pickard, C.J., Mauri, F., Phys. Rev. Lett. 88(08): 086403 (2002).

Reviews