NDRL Radiation Chemistry Data Center

Recent Papers in Radiation and Photochemistry

10/10/00

# 00_19

Kinetics Optical Spectra Thermodynamics
ESR Studies Excited States Photochemistry
Radiation Chemistry Related Experimental Studies Multiphase Systems
Polymers Biological and Medical Aspects Solar Energy
Industrial and Environmental Applications Theoretical Studies Reviews

Kinetics

A kinetic study of the reaction between 2-p-methoxyphenyl-4-phenyl-2-oxazolin-5-one and 2,2,6,6-tetramethyl-1-piperidinyl-N-oxide.
Zanocco, A.L., Canete, A., Melendez, M.X., Bol. Soc. Chil. Quim. 45(1): 123-9 (2000).

Primary photoisomerization reactions of 6-phenoxy-5,12-naphthacenequinone.
Malakhov, D.V., Gostev, F.E., Koroteev, N.I., Lozovoi, V.V., Magnitskii, S.A., Sarkisov, O.M., Tovbin, D.G., Titov, A.A., Chem. Phys. Rep. 18(7): 1217-32 (2000).

Direct determination of single-to-double stranded DNA ratio in solution applying time-resolved fluorescence measurements of dye-DNA complexes.
Cosa, G., Focsaneanu, K.S., McLean, J.R.N., Scaiano, J.C., Chem. Commun. (Cambridge) (8): 689-90 (2000).

Competition between photosensitization and charge transfer in soluble oligo(naphthylenevinylene)-fullerene dyads.
Segura, J.L., Gomez, R., Martin, N., Luo, C.P., Guldi, D.M., Chem. Commun. (Cambridge) (8): 701-2 (2000).

Kinetics of manganese(III) acetate in acetic acid: Generation of Mn(III) with Co(III), Ce(IV), and dibromide radicals; Reactions of Mn(III) with Mn(II), Co(II), hydrogen bromide, and alkali bromides.
Jiao, X.D., Espenson, J.H., Inorg. Chem. 39(7): 1549-54 (2000).

Ultrafast charge separation and exciplex formation induced by strong interaction between electron donor and acceptor at short distances.
Iwai, S., Murata, S., Katoh, R., Tachiya, M., Kikuchi, K., Takahashi, Y., J. Chem. Phys. 112(16): 7111-7 (2000).

Efficient charge separation in C60-based dyads: Triazolino[4',5':1,2][60]fullerenes.
Guldi, D.M., Gonzalez, S., Martin, N., Anton, A., Garin, J., Orduna, J., J. Org. Chem. 65(7): 1978-83 (2000).

Photochemistry of substituted benzyldiphenylphosphine oxides.
Zhao, N.N., Neckers, D.C., J. Org. Chem. 65(7): 2145-50 (2000).

Solvent as electron donor: Donor/acceptor electronic coupling is a dynamical variable.
Castner, E.W., Kennedy, D., Cave, R.J., J. Phys. Chem. A 104(13): 2869-85 (2000).

Radiation-induced and photosensitized splitting of C5-C5'-linked dihydrothymine dimers. 2. Conformational effects on the reductive splitting mechanism.
Ito, T., Shinohara, H., Hatta, H., Fujita, S., Nishimoto, S., J. Phys. Chem. A 104(13): 2886-93 (2000).

The [beta] C-C bond scission in alkoxy radicals: thermal unimolecular decomposition of t-butoxy radicals.
Fittschen, C., Hippler, H., Viskolcz, B., Phys. Chem. Chem. Phys. 2(8): 1677-83 (2000).

Photoinduced hydrogen- and electron-transfer processes between chloranil and aryl alkyl sulfides in organic solvents. Steady-state and time-resolved studies.
Del-Giacco, T., Elisei, F., Lanzalunga, O., Phys. Chem. Chem. Phys. 2(8): 1701-8 (2000).

Optical Spectra

Singlet-singlet excited-state absorption and triplet-triplet absorption of meso-tetraphenylporphine.
Gratz, H., Penzkofer, A., Chem. Phys. 254(2-3): 363-74 (2000).

Bistable charge-transfer complex formation of redox-active organic molecules based on intermolecular HOMO-LUMO interaction controlled by the redox reactions.
Uno, B., Okumura, N., Seto, K., J. Phys. Chem. A 104(13): 3064-72 (2000).

Thermodynamics

Charge separation in a molecular triad consisting of an iridium(III) - bis-terpy central core and porphyrins as terminal electron donor and acceptor groups.
Dixon, I.M., Collin, J.P., Sauvage, J.P., Barigelletti, F., Flamigni, L., Angew. Chem., Int. Ed. Engl. 39(7): 1292-5 (2000).

Probing the electronic structure of redox species and direct determination of intrinsic reorganization energies of electron transfer reactions.
Wang, X.B., Wang, L.S., J. Chem. Phys. 112(16): 6959-62 (2000).

Switching of pseudorotaxanes and catenanes incorporating a tetrathiafulvalene unit by redox and chemical inputs.
Balzani, V., Credi, A., Mattersteig, G., Matthews, O.A., Raymo, F.M., Stoddart, J.F., Venturi, M., White, A.J.P., Williams, D.J., J. Org. Chem. 65(7): 1924-36 (2000).

The electrochemically-driven decomplexation/recomplexation of inclusion adducts of ferrocene derivatives with an electron-accepting receptor.
Balzani, V., Becher, J., Credi, A., Nielsen, M.B., Raymo, F.M., Stoddart, J.F., Talarico, A.M., Venturi, M., J. Org. Chem. 65(7): 1947-56 (2000).

Long-range resonance energy transfer to [Ru(Bpy)3]2+.
Tyson, D.S., Gryczynski, I., Castellano, F.N., J. Phys. Chem. A 104(13): 2919-24 (2000).

Studying the dimerization reaction during the abstraction of halogen from organohalides by laser photoemission, controlled-potential electrolysis, and voltammetry.
Kurmaz, V.A., Krivenko, A.G., Tomilov, A.P., Turygin, V.V., Khudenko, A.V., Shalashova, N.N., Kotkin, A.S., Russ. J. Electrochem. (Transl. of Elektrokhimiya) 36(3): 308-15 (2000).

ESR Studies

The triplet wave function of C60 from W-band electron nuclear double resonance spectroscopy.
Dauw, X.L.R., van den Berg, G.J.B., van den Heuvel, D.J., Poluektov, O.G., Groenen, E.J.J., J. Chem. Phys. 112(16): 7102-10 (2000).

Splitting of degenerate orbitals of dibenzyl and tetrabenzyl adducts of C60: ESR of the radical anions and the rotation barriers of benzyl groups.
Fukuzumi, S., Suenobu, T., Gao, X., Kadish, K.M., J. Phys. Chem. A 104(13): 2908-13 (2000).

Unexpected radical generation on [gamma]-irradiating metastable forms of water at 77 K.
Plonka, A., Szajdzinska-Pietek, E., Bednarek, J., Hallbrucker, A., Mayer, E., Phys. Chem. Chem. Phys. 2(8): 1587-93 (2000).

Photochemistry

Photocontrol of triple-helix formation by using azobenzene-bearing oligo(thymidine).
Asanuma, H., Liang, X.G., Yoshida, T., Yamazawa, A., Komiyama, M., Angew. Chem., Int. Ed. Engl. 39(7): 1316-8 (2000).

Novel room light-induced disproportionation reaction of organo-ditin and -dilead compounds with organic dichalcogenides: an efficient salt-free route to organo-tin and -lead chalcogenides.
Mirzaci, F., Han, L.B., Tanaka, M., Chem. Commun. (Cambridge) (8): 657-8 (2000).

Utility of the tandem Pauson-Khand reaction in the construction of tetracycles.
Van Ornum, S.G., Bruendl, M.M., Cao, H., Reddy, M., Grubisha, D.S., Bennett, D.W., Cook, J.M., J. Org. Chem. 65(7): 1957-71 (2000).

Photoreactivity of 2-pyridones with furan, benzene, and naphthalene. Inter- and intramolecular photocycloadditions.
Sieburth, S.M., McGee, K.F., Zhang, F.N., Chen, Y.P., J. Org. Chem. 65(7): 1972-7 (2000).

Synthesis of aminocyclopentitols from chromium carbene complex derived aminocyclobutanones.
Wen, X., Norling, H., Hegedus, L.S., J. Org. Chem. 65(7): 2096-103 (2000).

Soluble, infrared-absorbing croconate dyes from 2,6-di-tert-butyl-4-methylchalcogenopyrylium salts.
Simard, T.P., Yu, J.H., Zebrowski-Young, J.M., Haley, N.F., Detty, M.R., J. Org. Chem. 65(7): 2236-8 (2000).

Photochemistry of N-heterocycles. 7 light induced reductive ring contractions of sixmembered cyclic iminium ions.
Nagy, J., Madarasz, Z., Rapp, R., Szollosy, A., Nyitrai, J., Dopp, D., J. Prakt. Chem./Chem.-Ztg. 342(3): 281-90 (2000).

Insertion products from photolysis of Tp'(CO)3WH and alkynes.
Frohnapfel, D.S., White, P.S., Templeton, J.L., Organometallics 19(8): 1497-506 (2000).

The N-(2-acetoxyethyl) group as a new photolabile protecting group.
Cossy, J., Rakotoarisoa, H., Tetrahedron Lett. 41(13): 2097-9 (2000).

(Alkynyl)dicobalt hexacarbonyl-mediated radical cyclizations.
Salazar, K.L., Nicholas, K.M., Tetrahedron 56(15): 2211-24 (2000).

Studies on chromium(0)-mediated three component cycloaddition reactions.
Rigby, J.H., Heap, C.R., Warshakoon, N.C., Tetrahedron 56(15): 2305-11 (2000).

Radiation Chemistry

Retrospective dosimetry: estimation of the dose to quartz using the single-aliquot regenerative-dose protocol.
Banerjee, D., Botter-Jensen, L., Murray, A.S., Appl. Radiat. Isot. 52(4): 831-44 (2000).

Annealing of [alpha]-decay damage in zircon: a Raman spectroscopic study.
Zhang, M., Salje, E.K.H., Capitani, G.C., Leroux, H., Clark, A.M., Schluter, J., Ewing, R.C., J. Phys.: Condens. Matter 12(13): 3131-48 (2000).

Amorphization of solids irradiated by fast neutrons.
Parkhomenko, V., Dubinin, S., Teploukhov, S., Goshchitskii, B., Physica B (Amsterdam) 276: 856-7 (2000).

Experimental Studies on Related Topics

Guided ion beam studies of electron and isotope transfer in N14+ + N152 collisions.
Glosik, J., Luca, A., Mark, S., Gerlich, D., J. Chem. Phys. 112(16): 7011-21 (2000).

Round trip radical reactions from acyclic precursors to tricyclo[5.3.1.0(2,6)]undecanes. A new cascade radical cyclization approach to (+)-isogymnomitrene and (+)-gymnomitrene.
Haney, B.P., Curran, D.P., J. Org. Chem. 65(7): 2007-13 (2000).

Oxidative cleavage of N,N-dimethylhydrazones to ketones with hydrogen peroxide, catalyzed by methyltrioxorhenium(VII).
Stankovic, S., Espenson, J.H., J. Org. Chem. 65(7): 2218-21 (2000).

Mass spectra of thioamides derived from resorcinol and its methyl ethers.
Sosnicki, J.G., Jagodzinski, T.S., Danikiewicz, W., Olejnik, M., Pol. J. Chem. 74(4): 483-93 (2000).

Multiphase Systems

Photoinduced reduction of nanoclusters of silver bromide and silver bis(2-ethylhexyl)sulfosuccinate in water droplets of reverse AOT micelles.
Krasovskii, A.N., Andreeva, A.I., Russ. J. Appl. Chem. 72(11): 1987-96 (1999).

Electrochemically directed self-assembly on gold.
Hsueh, C.C., Lee, M.T., Freund, M.S., Ferguson, G.S., Angew. Chem., Int. Ed. Engl. 39(7): 1227-30 (2000).

Photoinduced energy transfer in mixed self-assembled monolayers of pyrene and porphyrin.
Imahori, H., Nishimura, Y., Norieda, H., Karita, H., Yamazaki, I., Sakata, Y., Fukuzumi, S., Chem. Commun. (Cambridge) (8): 661-2 (2000).

Analysis of the first electron-removal states of Ba2Cu3O4C12 using polarization dependent angle-resolved photoelectron spectroscopy.
Haffner, S., Knupfer, M., Krishnakumar, S.R., Ruck, K., Krabbes, G., Golden, M.S., Fink, J., Johnson, R.L., Eur. Phys. J. B 14(2): 251-61 (2000).

Molecular rectification by a bimetallic Ru-Os compound anchored to nanocrystalline TiO2.
Kleverlaan, C., Alebbi, M., Argazzi, R., Bignozzi, C.A., Hasselmann, G.N., Meyer, G.J., Inorg. Chem. 39(7): 1342-3 (2000).

Quantification of the primary processes in aqueous heterogeneous photocatalysis using single-stage oxidation reactions.
Davydov, L., Smirniotis, P.G., J. Catal. 191(1): 105-15 (2000).

Adsorption and photocatalytic oxidation of acetone on TiO2: An in Situ transmission FT-IR study.
El-Maazawi, M., Finken, A.N., Nair, A.B., Grassian, V.H., J. Catal. 191(1): 138-46 (2000).

Orientation dependence of charge-transfer processes on TiO2 (Anatase) single crystals.
Hengerer, R., Kavan, L., Krtil, P., Gratzel, M., J. Electrochem. Soc. 147(4): 1467-72 (2000).

Nanocrystalline tungsten oxide thin film: Preparation, microstructure, and photochromic behavior.
Sun, M., Xu, N., Cao, Y.W., Yao, J.N., Wang, E.G., J. Mater. Res. 15(4): 927-33 (2000).

Photolithographic deposition of conducting gold films from thin amorphous films of AuPR3X (X = NO3, RCO2) on silicon surfaces.
Bravo-Vasquez, J.P., Hill, R.H., Polyhedron 19(3): 343-9 (2000).

Polymers

Effect of urea and thiourea derivatives on the photochemical stability of colorless and colored methyl methacrylate-methacrylic acid copolymers.
Serova, V.N., Cherkasova, O.A., Cherezova, E.N., Mukmeneva, N.A., Arkhireev, V.P., Russ. J. Appl. Chem. 72(11): 1997-2002 (1999).

Features of formation of photochromic layers based on complexes of bismuth chloride with carboxymethyl cellulose.
Komar, V.V., Russ. J. Appl. Chem. 72(11): 2016-9 (1999).

Three-dimensional optical data storage in a fluorescent dye-doped photopolymer.
Wang, M.M., Esener, S.C., Appl. Opt. 39(11): 1826-34 (2000).

Long-wavelength-absorbing dialkylphenacylsulfonium salt photoinitiators: Synthesis and photoinduced cationic polymerization.
Crivello, J.V., Kong, S.Q., J. Polym. Sci., Part A: Polym. Chem. 38(9): 1433-42 (2000).

Photoswitchable PEG-CA hydrogels and factors that affect their photosensitivity.
Andreopoulos, F.M., Beckman, E.J., Russell, A.J., J. Polym. Sci., Part A: Polym. Chem. 38(9): 1466-76 (2000).

Radiation grafting of styrene onto poly(vinylidene fluoride) films in propanol: The influence of solvent and synthesis conditions.
Walsby, N., Paronen, M., Juhanoja, J., Sundholm, F., J. Polym. Sci., Part A: Polym. Chem. 38(9): 1512-9 (2000).

Hydrogen production in [gamma]-ray and helium-ion radiolysis of polyethylene, polypropylene, poly(methyl-methacrylate), and polystyrene.
Chang, Z., Laverne, J.A., J. Polym. Sci., Part A: Polym. Chem. 38(9): 1656-61 (2000).

Formation of SnO2 thin film by pyrolysis of a photo-cross-linked organotin polymer.
Tamai, T., Ichinose, N., Macromolecules 33(7): 2505-8 (2000).

Release behavior of high molecular weight solutes from poly(ethylene glycol)-based degradable networks.
Lu, S.X., Anseth, K.S., Macromolecules 33(7): 2509-15 (2000).

Multifarious photoinduced morphologies in monomolecular films of azobenzene side chain polymer on mica.
Seki, T., Kojima, J., Ichimura, K., Macromolecules 33(7): 2709-17 (2000).

The influence of fast secondary electrons on the aromatic structure of polystyrene.
Siangchaew, K., Libera, M., Philos. Mag. A 80(4): 1001-16 (2000).

Ultrafast detection of charged photocarriers in conjugated polymers.
Moses, D., Dogariu, A., Heeger, A.J., Phys. Rev. B 61(14): 9373-9 (2000).

Biological and Medical Aspects

Theoretical studies on excited states of a phenolate anion in the environment of photoactive yellow protein.
He, Z., Martin, C.H., Birge, R., Freed, K.F., J. Phys. Chem. A 104(13): 2939-52 (2000).

Ultrafast energy transfer in LHC-II revealed by three-pulse photon echo peak shift measurements.
Agarwal, R., Krueger, B.P., Scholes, G.D., Yang, M., Yom, J., Mets, L., Fleming, G.R., J. Phys. Chem. B 104(13): 2908-18 (2000).

Temperature and free energy dependence of the direct charge recombination rate from the secondary quinone in bacterial reaction centers from Rhodobacter sphaeroides.
Schmid, R., Labahn, A., J. Phys. Chem. B 104(13): 2928-36 (2000).

Molecular assembly of covalently-linked mesoporphyrin dimers with light-harvesting polypeptides.
Kashiwada, A., Takeuchi, Y., Watanabe, H., Mizuno, T., Yasue, H., Kitagawa, K., Iida, K., Wang, Z.Y., Nozawa, T., Kawai, H., Nagamura, T., Kurono, Y., Nango, M., Tetrahedron Lett. 41(13): 2115-9 (2000).

Efficient chemical synthesis of a pyrimidine (6-4) pyrimidone photoproduct analog and its properties.
Satou, K., Komatsu, Y., Torizawa, T., Kato, K., Shimada, I., Nikaido, O., Ohtsuka, E., Tetrahedron Lett. 41(13): 2175-9 (2000).

Industrial and Environmental Applications

Fabrication of nanometric zinc pattern with photodissociated gas-phase diethylzinc by optical near field.
Yamamoto, Y., Kourogi, M., Ohtsu, M., Polonski, V., Lee, G.H., Appl. Phys. Lett. 76(16): 2173-5 (2000).

Photocatalytic behavior of WO3-loaded TiO2 in an oxidation reaction.
Kwon, Y.T., Song, K.Y., Lee, W.I., Choi, G.J., Do, Y.R., J. Catal. 191(1): 192-9 (2000).

Use of titanium dioxide as photocatalyst for photodegradation of sodium lauryl sulfate.
Ameta, S.C., Punjabi, P.B., Rao, P., Singhal, B., J. Indian Chem. Soc. 77(3): 157-60 (2000).

TiO2 supported on glass fiber for the photocatalytic degradation of benzamide.
Piscopo, A., Robert, D., Marzolin, C., Weber, J.V., J. Mater. Sci. Lett. 19(8): 683-4 (2000).

Atmospheric degradation of CF3OCF=CF2: Kinetics and mechanism of its reaction with OH radicals and Cl atoms.
Mashino, M., Kawasaki, M., Wallington, T.J., Hurley, M.D., J. Phys. Chem. A 104(13): 2925-30 (2000).

Radiation damage study using small-angle neutron scattering.
Retfalvi, E., Torok, G., Rosta, L., Physica B (Amsterdam) 276: 843-4 (2000).

Small angle scattering study concerning the effect of residual elements on the radiation behaviour of iron alloys.
Ulbricht, A., Bohmert, J., Grosse, M., Strunz, P., Physica B (Amsterdam) 276: 936-8 (2000).

SANS study of the microstructural evolution of martensitic steels under thermal ageing and neutron irradiation.
Mathon, M.H., Geoffroy, G., de Carlan, Y., Alamo, A., de Novion, C.H., Physica B (Amsterdam) 276: 939-40 (2000).

Theoretical Studies

On the triplet-singlet energy gap of acetylene.
Le, H.T., Flock, M., Nguyen, M.T., J. Chem. Phys. 112(16): 7008-10 (2000).

An ab initio study of the kinetics of the reactions of halomethanes with the hydroxyl radical. 1. CH2Br2.
Louis, F., Gonzalez, C.A., Huie, R.E., Kurylo, M.J., J. Phys. Chem. A 104(13): 2931-8 (2000).

Covalent anion of the canonical adenine-thymine base pair. Ab initio study.
Al-Jihad, I., Smets, J., Adamowicz, L., J. Phys. Chem. A 104(13): 2994-8 (2000).

Computational study of the unimolecular decomposition pathways of phenylperoxy radical.
Fadden, M.J., Barckholtz, C., Hadad, C.M., J. Phys. Chem. A 104(13): 3004-11 (2000).

Quantum coherent dynamics of molecules: A simple scenario for ultrafast photoisomerization - art. no. 040701.
Aalberts, D.P., de Jongh, M.S.L.D., Gerke, B.F., van Saarloos, W., Phys. Rev. A: At., Mol., Opt. Phys. 6104(4): 0701-4 (2000).

Diabatic and adiabatic potential-energy surfaces for azomethane photochemistry.
Cattaneo, P., Persico, M., Theor. Chem. Acc. 103(5): 390-8 (2000).

Reviews

Evaluated kinetic and photochemical data for atmospheric chemistry: Supplement VIII, halogen species - IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry.
Atkinson, R., Baulch, D.L., Cox, R.A., Hampson, R.F., Kerr, J.A., Rossi, M.J., Troe, J., J. Phys. Chem. Ref. Data 29(2): 167-266 (2000).

E-mail: ndrlrcdc.1@nd.edu
Author: K.P. Madden
Created: 7/2/97 Updated: 10/10/2000