NDRL Radiation Chemistry Data Center

Recent Papers in Radiation and Photochemistry

10/29/99

# 99_19

Kinetics Optical Spectra Thermodynamics
ESR Studies Excited States Photochemistry
Radiation Chemistry Related Experimental Studies Multiphase Systems
Polymers Biological and Medical Aspects Solar Energy
Industrial and Environmental Applications Theoretical Studies Reviews

Kinetics

Time-resolved CIDNP from photochemically generated radical ion pairs in rigid bichromophoric systems.
Wegner, M., Fischer, H., Koeberg, M., Verhoeven, J.W., Oliver, A.M., Paddon-Row, M.N., Chem. Phys. 242(2): 227-34 (1999).

Microwave field effects on the time dependence of recombination fluorescence from non-polar solutions.
Anishchik, S.V., Borovkov, V.I., Ivannikov, V.I., Shebolaev, I.V., Chernousov, Y.D., Lukzen, N.N., Anisimov, O.A., Molin, Y.N., Chem. Phys. 242(3): 319-30 (1999).

The reaction of methyl radicals with hydrogen peroxide.
Ulanski, P., Merenyi, G., Lind, J., Wagner, R., von Sonntag, C., J. Chem. Soc., Perkin Trans. 2 (4): 673-6 (1999).

The radical-induced decomposition of 2-methoxyphenol.
Dorrestijn, E., Mulder, P., J. Chem. Soc., Perkin Trans. 2 (4): 777-80 (1999).

Photodynamics of the Paterno-Buchi cycloaddition of stilbene to quinone. Unusual modulation of electron-transfer kinetics by solvent and added salt.
Hubig, S.M., Sun, D.L., Kochi, J.K., J. Chem. Soc., Perkin Trans. 2 (4): 781-8 (1999).

Kinetic study on the reaction of tributylphosphine with methylviologen. Reactivity of the phosphine radical cation intermediate towards nucleophiles.
Yasui, S., Shioji, K., Tsujimoto, M., Ohno, A., J. Chem. Soc., Perkin Trans. 2 (4): 855-62 (1999).

Solvent effect on kinetics of the chloride ion cleavage from anion radicals of 4-chlorobenzophenone.
Jaworski, J.S., Leszczynski, P., J. Electroanal. Chem. Interfacial Electrochem. 464(2): 259-62 (1999).

Oxetanes from [2+2] cycloaddition of stilbenes to quinone via photoinduced electron transfer.
Sun, D.L., Hubig, S.M., Kochi, J.K., J. Org. Chem. 64(7): 2250-8 (1999).

Chemoselective lactam formation in the addition of benzenesulfonyl bromide to N-allyl acrylamides and N-allyl 3,3-dimethylacrylamides.
Wang, C., Russell, G.A., J. Org. Chem. 64(7): 2346-52 (1999).

Gallic esters of sucrose as a new class of antioxidants.
Potier, P., Maccario, V., Giudicelli, M.B., Queneau, Y., Dangles, O., Tetrahedron Lett. 40(17): 3387-90 (1999).


Optical Spectra

Visible and near-infrared absorption spectra of singly and doubly reduced C76 fullerene anions.
Gao, X.A., Van Caemelbecke, E., Kadish, K.M., Electrochem. Solid-State Lett. 1(5): 222-3 (1998).

Fluorescence properties of an electron acceptor substituted bis-pyrazolo-pyridine derivative: NO2-DMPP.
Rechthaler, K., Schamschule, R., Parusel, A.B.J., Rotkiewicz, K., Piorun, D., Kohler, G., Acta Phys. Pol., A 95(3): 321-34 (1999).

Zinc-tetrabenzoporphyrine-doped poly(methyl methacrylate): a new photochromic recording medium.
Khodykin, O.V., Zilker, S.J., Haarer, D., Kharlamov, B.M., Opt. Lett. 24(8): 513-5 (1999).

Influence of hydrostatic pressure and temperature on two-photon absorption of a C60-2-thioxo-1,3-dithiole cycloadduct.
Sahraoui, B., Kityk, I.V., Phu, X.N., Hudhomme, P., Gorgues, A., Phys. Rev. B, Condens. Matter 59(14): 9229-38 (1999).


ESR Studies

Photogeneration of atomic hydrogen in rare gas matrices.
Eloranta, J., Vaskonen, K., Kunttu, H., J. Chem. Phys. 110(16): 7917-25 (1999).

The radical ions of acenaphtho[1,2-b][1,4]dithiine derivatives and acenaphtho[1,2-b][1,4]oxathiine: Solution EPR and ENDOR studies. The X-ray crystal structures of 8,9-bis(methylsulfanyl)acenaphtho[1,2-b][1,4]dithiine and its complexes with 7,7,8,8-tetracyano-p-quinodimethane (TCNQ), 2,5-dibromo-TCNQ and iodine.
Bryce, M.R., Lay, A.K., Chesney, A., Batsanov, A.S., Howard, J.A.K., Buser, U., Gerson, F., Merstetter, P., J. Chem. Soc., Perkin Trans. 2 (4): 755-63 (1999).

The kinetics and thermodynamics of quinone-semiquinone-hydroquinone systems under physiological conditions.
Roginsky, V.A., Pisarenko, L.M., Bors, W., Michel, C., J. Chem. Soc., Perkin Trans. 2 (4): 871-6 (1999).

Kinetics of nitroxide-mediated pseudoliving radical styrene polymerization.
Zaremskii, M.Y., Stoyachenko, Y.I., Plutalova, A.V., Lachinov, M.B., Golubev, V.B., Vysokomol. Soedin., Ser. A 41(3): 389-98 (1999).


Excited States

Molecular and crystal structure of two anthracene derivatives and their 1,4-endoperoxides. Influence of the aromatic ring distortion upon the steric acceleration of the 1,4-addition of singlet oxygen.
Lahrahar, N., Bouas-Laurent, H., Desvergne, J.P., Marsau, P., Rigaudy, J., Aust. J. Chem. 52(3): 213-8 (1999).

Formation and stabilization of F centers following direct generation of self-trapped excitons in KCl crystals.
Kudryavtseva, I.A., Vasilchenko, E.A., Lushchik, A.C., Lushchik, C.B., Phys. Solid State 41(3): 388-95 (1999).


Photochemistry

The efficient synthesis of 1,2-dioxetanes from indene and 1,2-dihydronaphthalene.
Jefford, C.W., Deheza, M.F., Heterocycles 50(2): 1025-31 (1999).

Kinetics of copper incorporation into an engineered purple azurin.
Wang, X.T., Ang, M.C., Lu, Y., J. Am. Chem. Soc. 121(12): 2947-8 (1999).

Mechanistic studies on PET-oxidative cyclization of unsaturated silyl enol ethers: dependence of the regioselectivity on alcohol addition and pressure effects.
Ackermann, L., Heidbreder, A., Wurche, F., Klarner, F.G., Mattay, J., J. Chem. Soc., Perkin Trans. 2 (4): 863-9 (1999).

A new synthesis of cis-cyclobut-3-ene-1,2-dicarboxylic anhydride.
Gauvry, N., Comoy, C., Lescop, C., Huet, F., Synthesis (4): 574-6 (1999).

The new and simple 'LEGO' system: Synthesis and reactions of thienyl-substituted 4-tributylstannyl-2,6-oligopyridines.
Pabst, G.R., Pfuller, O.C., Sauer, J., Tetrahedron 55(16): 5047-66 (1999).

A convenient synthesis of 18-hydroxycorticosterone and 18-hydroxy-11-desoxycorticosterone via stereospecific hypoiodination of 20-hydroxysteroids.
Boudi, A., Lemoine, P., Viossat, B., Tomas, A., Fiet, J., Galons, H., Tetrahedron 55(16): 5171-6 (1999).

Adaptation of the photo-induced [1,3]-allylic phenylthio shift to the preparation of functionalized diquinanes.
Usui, S., Paquette, L.A., Tetrahedron Lett. 40(18): 3495-8 (1999).

Intramolecular photocycloaddition of 1,3-dienes with 2-pyridones.
Sieburth, S.M., Zhang, F.N., Tetrahedron Lett. 40(18): 3527-30 (1999).


Radiation Chemistry

Change in chemical bonding states in electron-irradiated graphite.
Muto, S., Takeuchi, M., Tanabe, T., Kurata, H., Hojou, K., Jpn. J. Appl. Phys. 38(3A): 1514-5 (1999).

Creating primary defects in calcium fluoride crystals with various prehistories, using pulsed electron irradiation.
Chinkov, E.P., Shtanko, V.F., Phys. Solid State 41(3): 396-403 (1999).


Experimental Studies on Related Topics

A radical route to morphans. Synthesis and spectroscopic data of the 2-azabicyclo[3.3.1]nonane.
Quirante, J., Escolano, C., Diaba, F., Bonjoch, J., Heterocycles 50(2): 731-8 (1999).

[C2H4OS]+ radical cations derived from alkyl thioformates: tandem mass spectrometry and molecular orbital calculations.
Lahem, D., Flammang, R., Le, H.T., Nguyen, T.L., Nguyen, M.T., J. Chem. Soc., Perkin Trans. 2 (4): 821-6 (1999).

Toluene and isotoluene radical cations: Alkoxymethyl substituents as a probe to study the formation, fragmentation and isomerization.
Harting, N., Grutzmacher, H.F., J. Mass Spectrom. 34(4): 408-20 (1999).

Radical-mediated construction of cyclopentane with concurrent formation of a well-defined quaternary center.
Zhu, Q., Qiao, L.X., Wu, Y.K., Wu, Y.L., J. Org. Chem. 64(7): 2428-32 (1999).

Oxidative activation in aromatic substitutions. Reactions of N,N-dimethylanilines with secondary anilines promoted by thallium triacetate.
Ciminale, F., Ciardo, A., Francioso, S., Nacci, A., J. Org. Chem. 64(7): 2459-64 (1999).

Strong alignment effect in quasiresonant charge transfer between laser-excited sodium atoms and C60.
Heusler, G., Campbell, E.E.B., Phys. Rev. Lett. 82(16): 3236-9 (1999).

Synthesis of phenethylenamides and their radical cyclization to 3-benzazepines.
Cid, M.M., Dominguez, D., Castedo, L., Vazquez-Lopez, E.M., Tetrahedron 55(17): 5599-610 (1999).

Intramolecular radical allylation with allylic sulfones - A synthesis of +/--botryodiplodin.
Nouguier, R., Gastaldi, S., Stien, D., Bertrand, M., Renaud, P., Tetrahedron Lett. 40(17): 3371-4 (1999).

Diastereoselective radical cyclization of bromoacetals: Efficient synthesis of +/--botryodiplodin.
Villar, F., Andrey, O., Renaud, P., Tetrahedron Lett. 40(17): 3375-8 (1999).

Ring expansion reactions via endocyclic cleavage of cyclopropylcarbinyl radicals.
Lee, P.H., Lee, B., Lee, J., Park, S.K., Tetrahedron Lett. 40(17): 3427-30 (1999).

Tandem use of reductive and radical cyclization protocols in an approach to the first [sigma]-allyl cation.
Paquette, L.A., Usui, S., Tetrahedron Lett. 40(18): 3499-502 (1999).

A new radical synthesis of allenes.
Delouvrie, B., Lacote, E., Fensterbank, L., Malacria, M., Tetrahedron Lett. 40(18): 3565-8 (1999).


Multiphase Systems

Chemical modeling of photocatalytically active center on the silica surface.
Artemev, Y.M., Kuzmin, G.N., Russ. J. Appl. Chem. 71(11): 1938-41 (1998).

Photoelectrochemical response and stability of titanium-zinc mixed oxide films formed by thermal oxidation.
Saeki, I., Setaka, J., Furuichi, R., Konno, H., J. Electroanal. Chem. Interfacial Electrochem. 464(2): 238-44 (1999).

Synthesis of PbS/polyacrylonitrile nanocomposites at room temperature by [gamma]-irradiation.
Qiao, Z.P., Xie, Y., Zhu, Y.J., Qian, Y., J. Mater. Chem. 9(4): 1001-2 (1999).

Titanium dioxide synthesis by sol gel methods and evaluation of their photocatalytic activity.
Robert, D., Weber, J.V., J. Mater. Sci. Lett. 18(2): 97-8 (1999).

The photoelectrochemistry of Nd3+-doped TiO2 nanocrystalline electrodes.
Wang, Y.Q., Cheng, H.M., Hao, Y.Z., Ma, J.M., Xu, B., Li, W.H., Cai, S.M., J. Mater. Sci. Lett. 18(2): 127-9 (1999).

Light-induced transformation of C60 films in the presence and absence of oxygen.
Makarova, T.L., Sakharov, V.I., Serenkov, I.T., Vul, A.Y., Phys. Solid State 41(3): 497-500 (1999).

The enhancement of redox reactions with mixed oxide catalysts by the sol-gel process.
Jeon, M.S., Lee, T.K., Kim, D.H., Joo, H., Kim, H.T., Sol. Energy Mater. Sol. Cells 57(3): 217-27 (1999).

Effect of co-adsorbed water on photodimerization and photooxygenation of 4-methoxystyrene included in NaY.
Matsubara, C., Kojima, M., Tetrahedron Lett. 40(17): 3439-42 (1999).


Polymers

Effect of [gamma]-irradiation on thermomechanical properties of ultrahigh-molecular-weight polyethylene with different molecular weights.
Polikarpov, A.P., Valendo, A.Y., Russ. J. Appl. Chem. 71(11): 1991-5 (1998).

Surface grafting of poly(vinylamine) onto poly(ethylene) film by corona discharge-induced grafting.
Seto, F., Muraoka, Y., Akagi, T., Kishida, A., Akashi, M., J. Appl. Polym. Sci. 72(12): 1583-7 (1999).

Polymerization of methyl methacrylate at high temperature with 1-butanethiol as chain transfer agent.
Fenouillot, F., Terrisse, J., Rimlinger, T., J. Appl. Polym. Sci. 72(12): 1589-99 (1999).

Copolymerization with depropagation: Prediction of kinetics and properties of [alpha]-methylstyrene-methyl methacrylate copolymers. II. Bulk copolymerization.
Martinet, F., Guillot, J., J. Appl. Polym. Sci. 72(12): 1611-25 (1999).

Copolymerization of [alpha]-methylstyrene with methyl methacrylate. III. Emulsion process: Experimental data on kinetics, particle size, composition, molecular weight, and glass transition temperature.
Martinet, F., Guillot, J., J. Appl. Polym. Sci. 72(12): 1627-43 (1999).

Surface modification of poly(ether sulfone) ultrafiltration membranes by low-temperature plasma-induced graft polymerization.
Chen, H., Belfort, G., J. Appl. Polym. Sci. 72(13): 1699-711 (1999).

Order parameter of liquid crystal on polyimide with polarized ultraviolet-light exposure.
Nishikawa, M., West, J.L., Jpn. J. Appl. Phys., Part 2 38(3B): L331-L3 (1999).

Effect of chemical structures of polyimides on unidirectional liquid crystal alignment produced by a polarized ultraviolet-light exposure.
Nishikawa, M., Kosa, T., West, J.L., Jpn. J. Appl. Phys., Part 2 38(3B): L334-L7 (1999).

Synthesis of silsesquioxanes having photochromic dithienylethene pendant groups.
Nakashima, H., Irie, M., Macromol. Chem. Phys. 200(4): 683-92 (1999).

Formation of SnO2 by pyrolysis of a polymer network containing organotin groups.
Tamai, T., Ichinose, N., Agari, Y., Macromol. Rapid Commun. 20(4): 179-81 (1999).

Crosslinkable hole-transport materials for preparation of multilayer organic light emitting devices by spin-coating.
Bayerl, M.S., Braig, T., Nuyken, O., Muller, D.C., Gross, M., Meerholz, K., Macromol. Rapid Commun. 20(4): 224-8 (1999).

Photogeneration action spectroscopy of neutral and charged excitations in films of a ladder-type poly(para-phenylene).
Wohlgenannt, M., Graupner, W., Leising, G., Vardeny, Z.V., Phys. Rev. Lett. 82(16): 3344-7 (1999).

Photophysical properties and photoinduced polymerisation activity of novel 1-chloro-4-oxy/acyloxythioxanthone initiators.
Allen, N.S., Salleh, N.G., Edge, M., Shah, M., Ley, C., Morlet-Savary, F., Fouassier, J.P., Catalina, F., Green, A., Navaratnam, S., Parsons, B.J., Polymer 40(15): 4181-93 (1999).

Weak response measurements of photosensitive media.
Barmenkov, Y.O., Starodumov, A.N., Santoyo, F.M., Kozhevnikov, N.M., Rev. Mex. Fis. 45(2): 140-5 (1999).

Photochromic liquid-crystalline copolymers bearing cinnamic acid-based chiral side groups.
Bobrovskii, A.Y., Boiko, N.I., Shibaev, V.P., Schaumburg, K., Vysokomol. Soedin., Ser. A 41(2): 197-208 (1999).

Radiation-induced depolymerization of PMMA adsorbed on silochrome silochrome.
Bruk, M.A., Kondrateva, M.V., Baranov, A.A., Pebalk, K.V., Sergeev, A.M., Kozlova, N.V., Vysokomol. Soedin., Ser. A 41(2): 256-62 (1999).

Non-Langevin recombination and dose effects in the radiation-induced conductivity of polymers.
Tyutnev, A.P., Saenko, V.S., Pozhidaev, E.D., Vysokomol. Soedin., Ser. A 41(2): 332-9 (1999).

Constant of equilibrium reversible inhibition in nitroxyl-mediated pseudoliving radical copolymerization of styrene with butyl acrylate.
Plutalova, A.V., Zaremskii, M.Y., Pavlov, M.G., Garina, E.S., Lachinov, M.B., Golubev, V.B., Vysokomol. Soedin., Ser. A 41(3): 552-5 (1999).


Biological and Medical Aspects

Investigation of hydroxyl radical-induced cross-linking of peptides and its inhibition by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry.
Kim, H.J., Park, S., Bull. Korean Chem. Soc. 20(3): 370-2 (1999).

Electrocatalytic oxidation of dihydronicotinamide adenine dinucleotide with ferrocene carboxylic acid by diaphorase from Clostridium kluveri. Remarks on the kinetic approaches usually adopted.
Antiochia, R., Lavagnini, I., Magno, F., Electroanalysis 11(2): 129-33 (1999).

Kinetics of 2'-deoxynridin-1'-yl radical reactions.
Emanuel, C.J., Newcomb, M., Ferreri, C., Chatgilialoglu, C., J. Am. Chem. Soc. 121(12): 2927-8 (1999).

Bacteriorhodopsin and rhodopsin studied by incoherent neutron scattering: dynamical properties of ground states and light activated intermediates.
Fitter, J., Verclas, S.A.W., Lechner, R.E., Buldt, G., Ernst, O.P., Hofmann, K.P., Dencher, N.A., Physica B (Amsterdam) 266(1-2): 35-40 (1999).


Solar Energy

Efficient CuInSe2 solar cells fabricated by a novel ink coating approach.
Basol, B.M., Kapur, V.K., Norsworthy, G., Halani, A., Leidholm, C.R., Roe, R., Electrochem. Solid-State Lett. 1(6): 252-4 (1998).

All-solid-state photoelectrochemical cell based on a polymer electrolyte containing a new transparent and highly electropositive redox couple.
Philias, J.M., Marsan, B., Electrochim. Acta 44(17): 2915-26 (1999).

Activity analysis of mononuclear ruthenium ammine complex dispersed in a polymer membrane as an electrochemical water oxidation catalyst.
Kinoshita, K., Yagi, M., Kaneko, M., J. Mol. Catal. A: Chem. 142(1): 1-5 (1999).

Donor-acceptor interaction between non-aqueous solvents and I2 to generate I3-, and its implication in dye sensitized solar cells.
Kebede, Z., Lindquist, S.E., Sol. Energy Mater. Sol. Cells 57(3): 259-75 (1999).


Industrial and Environmental Applications

Development of capillary electrophoresis methods for the analysis of fluoroquinolones and application to the study of the influence of humic substances on their photodegradation in aqueous phase.
Schmitt-Kopplin, P., Burhenne, J., Freitag, D., Spiteller, M., Kettrup, A., J. Chromatogr., A 837(1-2): 253-65 (1999).

Microfabrication by use of a spatial light modulator in the ultraviolet: experimental results.
Farsari, M., Huang, S., Birch, P., Claret-Tournier, F., Young, R., Budgett, D., Bradfield, C., Chatwin, C., Opt. Lett. 24(8): 549-50 (1999).


Theoretical Studies

Excited states of intermolecular electron-donor-acceptor systems and internal geometry of complex components.
Deperasinska, I., Sobieraj, A., Acta Phys. Pol., A 95(3): 309-19 (1999).

Towards a unitary description of the photochemical isomerization reactions in pentaatomic aromatic heterocycles: The case of furan, thiophene, pyrrole, isoxazole, imidazole, and pyrazole derivatives.
D'Auria, M., Heterocycles 50(2): 1115-36 (1999).

Effect of structures of bipyridinium salts an redox potential and its application to CO2 fixation.
Kodaka, M., Kubota, Y., J. Chem. Soc., Perkin Trans. 2 (4): 891-4 (1999).

AM1, INDO/S and optical studies of carbocations of carotenoid molecules. Acid induced isomerization.
Konovalov, V.V., Kispert, L.D., J. Chem. Soc., Perkin Trans. 2 (4): 901-9 (1999).

Time oscillations of escape rates in periodically driven systems.
Smelyanskiy, V.N., Dykman, M.I., Golding, B., Phys. Rev. Lett. 82(16): 3193-7 (1999).

Water molecule dipole in the gas and in the liquid phase.
Silvestrelli, P.L., Parrinello, M., Phys. Rev. Lett. 82(16): 3308-11 (1999).


Reviews

Second generation drugs and additional applications of PDT.
Miller, J., J. Chem. Educ. 76(5): 594 (1999).

Linkers for solid phase organic synthesis.
James, I.W., Tetrahedron 55(16): 4855-946 (1999).

The mechanism of the directing influence of functional groups and the geometry of reactant molecules on the peroxide epoxidation of alkenes.
Dryuk, V.G., Kartsev, V.G., Usp. Khim. 68(3): 206-26 (1999).


E-mail: ndrlrcdc.1@nd.edu
Author: K.P. Madden
Created: 7/2/97 Updated: 10/29/1999