N-(2-Acetylphenyl)acetamide

Pileni, M.P.; Santus, R.; Land, E.J.
265 nm Laser flash photolysis of some ortho-substituted anilides and related N-formylkynurenine derivatives.
Photochem. Photobiol. 27: 671-81 (1978)

N-(2-Acetylphenyl)acetamide
Solvent : EtOH

wave length at maximum = 430 nm

Triplet state population method: Pulsed laser photolysis
Lifetime = 10 micro sec.
Comments: *Oxygen quenching (5.6 x 108 L mol–1 s–1)

Pileni, M.P.
Electronic, photophysical, and photochemical properties of ortho-substituted anilides.
Bull. Soc. Chim. Fr. (11-12 Pt. 2): 545-51 (1980)

N-(2-Acetylphenyl)acetamide
Solvent : EtOH

wave length at maximum = 430 nm

Triplet state population method: Pulsed laser photolysis
Lifetime = 10 micro sec.
Comments: *Oxygen quenching (5.6 x 108 L mol–1 s–1)

Pileni, M.P.; Santus, R.; Land, E.J.
265 nm Laser flash photolysis of some ortho-substituted anilides and related N-formylkynurenine derivatives.
Photochem. Photobiol. 27: 671-81 (1978)

N-(2-Acetylphenyl)acetamide
Solvent : Hexane

wave length (nm) at maximum, extinction coefficient = 450, 8900

Triplet state population method: Pulsed laser photolysis
Extinction coefficient estimation method: Total depletion
Lifetime = 8.5 micro sec.
Oscillator strength = 0.18.

Pileni, M.P.
Electronic, photophysical, and photochemical properties of ortho-substituted anilides.
Bull. Soc. Chim. Fr. (11-12 Pt. 2): 545-51 (1980)

N-(2-Acetylphenyl)acetamide
Solvent : Hexane

wave length at maximum = 450 nm

Triplet state population method: Pulsed laser photolysis
Lifetime = 8.5 micro sec.

Pileni, M.P.; Santus, R.; Land, E.J.
265 nm Laser flash photolysis of some ortho-substituted anilides and related N-formylkynurenine derivatives.
Photochem. Photobiol. 27: 671-81 (1978)

N-(2-Acetylphenyl)acetamide
Solvent : Water, pH = 7.5

wave length at maximum = 430 nm

Triplet state population method: Pulsed laser photolysis
Lifetime = 6.5 micro sec.
Comments: *Oxygen quenching (2.2 x 109 L mol–1 s–1); ionic strength 0.01 mol L–1

Pileni, M.P.
Electronic, photophysical, and photochemical properties of ortho-substituted anilides.
Bull. Soc. Chim. Fr. (11-12 Pt. 2): 545-51 (1980)

N-(2-Acetylphenyl)acetamide
Solvent : Water, pH = 7.5

wave length at maximum = 430 nm

Triplet state population method: Pulsed laser photolysis
Lifetime = 6.5 micro sec.
Comments: *Oxygen quenching (2.2 x 109 L mol–1 s–1); ionic strength 0.01 mol L–1

* Evidence supporting the assignment of the transient triplet state.
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