Phenylhydrazine Singlet oxygen

Byteva, I.M.; Salokhiddinov, K.I.
Opt. Spectrosc. (USSR) 49, 387-390 (1980)

Reaction: C₆H₅NHNH₂ + ¹O₂^* ® products
Solvent: Pyridine

k_react = 1.4 × 10⁸(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = TPP, MPDEE or PdMP; meas. quantum yield of oxidation = quantum yield of singlet oxygen formation.

Byteva, I.M.; Salokhiddinov, K.I.
Opt. Spectrosc. (USSR) 49, 387-390 (1980)

Reaction: C₆H₅NHNH₂ + ¹O₂^* ® products and/or physical quenching
Solvent: Carbon tetrachloride

k = 8.6 × 10⁶(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Mesoporphyrin IX, diethyl ester.

Byteva, I.M.; Salokhiddinov, K.I.
Opt. Spectrosc. (USSR) 49, 387-390 (1980)

Reaction: C₆H₅NHNH₂ + ¹O₂^* ® products
Solvent: Acetone

k_react = 9 × 10⁷(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = TPP, MPDEE or PdMP; meas. quantum yield of oxidation = quantum yield of singlet oxygen formation.

Byteva, I.M.; Salokhiddinov, K.I.
Opt. Spectrosc. (USSR) 49, 387-390 (1980)

Reaction: C₆H₅NHNH₂ + ¹O₂^* ® products and/or physical quenching
Solvent: Chloroform

k = 7.5 × 10⁶(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = TPP, MPDEE or PdMP.