1-Isopropylamino-4-phenylaminobenzene Singlet oxygen

Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
Can. J. Chem. 52, 3728-3737 (1974)

Reaction: 1-Isopropylamino-4-phenylaminobenzene + ¹O₂^* ® products and/or physical quenching
Solvent: Hexadecane

k = 4.0 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Discharge
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = Rubrene; k for indicator = 7.3 × 10⁷ L/(mol·s); used solvent k_d = 9.0 × 10⁴ s^-1.

Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
Can. J. Chem. 52, 3728-3737 (1974)

Reaction: 1-Isopropylamino-4-phenylaminobenzene + ¹O₂^* ® products and/or physical quenching
Solvent: Isooctane

k = 2.1 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 4.7 × 10⁴ s^-1; k for indicator = 7.3 × 10⁷ L/(mol·s).

Carlsson, D.J.; Suprunchuk, T.; Wiles, D.M.
J. Polym. Sci., Polym. Lett. Ed. 11, 61-65 (1973)

Reaction: 1-Isopropylamino-4-phenylaminobenzene + ¹O₂^* ® products and/or physical quenching
Solvent: Isooctane

k = 3.3 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 4 × 10⁴ s^-1; k for indicator = 7 × 10⁷ L/(mol·s).

Dalle, J.P.; Magous, R.; Mousseron-Canet, M.
Photochem. Photobiol. 15, 411-419 (1972)

Reaction: 1-Isopropylamino-4-phenylaminobenzene + ¹O₂^* ® products and/or physical quenching
Solvent: EtOH

k = 6.7 × 10⁹(L mol^-1 s^-1), T = 273K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Methylene Blue; Indicator = 2,5-Dimethylfuran; used solvent k_d = 7.9 × 10⁴ s^-1; k for indicator = 5.3 × 10⁸ L/(mol·s); k calcd. in [81WIL/BRU].