Benzylamine Singlet oxygen

Clennan, E.L.; Noe, L.J.; Wen, T.; Szneler, E.
J. Org. Chem. 54, 3581-3584 (1989)

Reaction: C₆H₅CH₂NH₂ + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CN

k = 1.7 × 10⁶(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Rose Bengal dianion. [Sensitizer] = 3-9 × 10^-5 (mol L^-1).

Clennan, E.L.; Noe, L.J.; Wen, T.; Szneler, E.
J. Org. Chem. 54, 3581-3584 (1989)

Reaction: C₆H₅CH₂NH₂ + ¹O₂^* ® products and/or physical quenching
Solvent: (CH₃)₂CHOH

k = 9.6 × 10⁴(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Rose Bengal dianion. [Sensitizer] = 3-9 × 10^-5 (mol L^-1).

Young, R.H.; Martin, R.L.; Feriozi, D.; Brewer, D.; Kayser, R.
Photochem. Photobiol. 17, 233-244 (1973)

Reaction: C₆H₅CH₂NH₂ + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 2.6 × 10⁵(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements using indicator

Photosensitizer = Rose Bengal dianion; Indicator = 1,3-Diphenylisobenzofuran; used solvent k_d = 9.0 × 10⁴ s^-1.

Dalle, J.P.; Magous, R.; Mousseron-Canet, M.
Photochem. Photobiol. 15, 411-419 (1972)

Reaction: C₆H₅CH₂NH₂ + ¹O₂^* ® products and/or physical quenching
Solvent: EtOH

k = < 1 × 10⁹(L mol^-1 s^-1), T = 273K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Limiting value

Photosensitizer = Methylene Blue; Indicator = 2,5-Dimethylfuran; No measurable effect.