N,N-Dimethylisobutenylamine Singlet oxygen

Foote, C.S.; Dzakpasu, A.A.; Lin, J.W.-P.
Tetrahedron Lett., 1247-1250 (1975)

Reaction: N,N-Dimethylisobutenylamine + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: C₆H₆

k_react = 4.8 × 10⁸(L mol^-1 s^-1), k_reference = 4.8 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphinatozinc(II).

Foote, C.S.; Dzakpasu, A.A.; Lin, J.W.-P.
Tetrahedron Lett., 1247-1250 (1975)

Reaction: N,N-Dimethylisobutenylamine + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: C₆H₆, 5%, CH₃CN, 95%

k/k_reference = 9.4

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphinatozinc(II); meas. k/k_ref = 9.4.

Foote, C.S.; Dzakpasu, A.A.; Lin, J.W.-P.
Tetrahedron Lett., 1247-1250 (1975)

Reaction: N,N-Dimethylisobutenylamine + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: C₆H₆, 80%, CH₃CN, 20%

k/k_reference = 7.8

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphinatozinc(II); meas. k/k_ref = 7.8.

Foote, C.S.; Dzakpasu, A.A.; Lin, J.W.-P.
Tetrahedron Lett., 1247-1250 (1975)

Reaction: N,N-Dimethylisobutenylamine + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: C₆H₆, 20%, DMSO, 80%

k/k_reference = 9.1

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphinatozinc(II); meas. k/k_ref = 9.1.

Foote, C.S.; Dzakpasu, A.A.; Lin, J.W.-P.
Tetrahedron Lett., 1247-1250 (1975)

Reaction: N,N-Dimethylisobutenylamine + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: C₆H₆, 60%, DMSO, 40%

k/k_reference = 7.6

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphinatozinc(II); meas. k/k_ref = 7.6.

Foote, C.S.; Dzakpasu, A.A.; Lin, J.W.-P.
Tetrahedron Lett., 1247-1250 (1975)

Reaction: N,N-Dimethylisobutenylamine + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: C₆H₆, 80%, DMSO, 20%

k/k_reference = 11

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphinatozinc(II); meas. k/k_ref = 11.

Foote, C.S.; Dzakpasu, A.A.; Lin, J.W.-P.
Tetrahedron Lett., 1247-1250 (1975)

Reaction: N,N-Dimethylisobutenylamine + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: C₆H₆, 30%, MeOH, 70%

k/k_reference = 2.9

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphinatozinc(II); meas. k/k_ref = 2.9.

Foote, C.S.; Dzakpasu, A.A.; Lin, J.W.-P.
Tetrahedron Lett., 1247-1250 (1975)

Reaction: N,N-Dimethylisobutenylamine + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: C₆H₆, 5%, MeOH, 95%

k/k_reference = 2.2

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphinatozinc(II); meas. k/k_ref = 2.2.

Foote, C.S.; Dzakpasu, A.A.; Lin, J.W.-P.
Tetrahedron Lett., 1247-1250 (1975)

Reaction: N,N-Dimethylisobutenylamine + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: C₆H₆, 5%, n-C₅H₁₂, 95%

k/k_reference = 7.1

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphinatozinc(II); meas. k/k_ref = 7.1.