Tributylamine Singlet oxygen

Iu, K.-K.; Thomas, J.K.
J. Am. Chem. Soc. 112, 3319-3325 (1990)

Reaction: [CH₃(CH₂)₃]₃N + ¹O₂^* ® products and/or physical quenching
Solvent: Cyclohexane

k = 3.0 × 10⁷(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = 2'-Acetonaphthone.

Monroe, B.M.
J. Phys. Chem. 81, 1861-1864 (1977)

Reaction: [CH₃(CH₂)₃]₃N + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 5.8 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).

Dalle, J.P.; Magous, R.; Mousseron-Canet, M.
Photochem. Photobiol. 15, 411-419 (1972)

Reaction: [CH₃(CH₂)₃]₃N + ¹O₂^* ® products and/or physical quenching
Solvent: EtOH

k = < 1 × 10⁹(L mol^-1 s^-1), T = 273K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Methylene Blue; Indicator = 2,5-Dimethylfuran; No measurable effect.