[26] Porphyrin Singlet oxygen

Schermann, G.; Schmidt, R.; Voelcker, A.; Brauer, H.-D.; Mertes, H.; Franck, B.
Photochem. Photobiol. 52, 741-744 (1990)

Reaction: [26] Porphyrin + ¹O₂^* ® products and/or physical quenching
Solvent: Chloroform

k = 4.2 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: infrared luminescence
Data type: Derived from steady state measurements
Excitation wavelength: 546 nm

Self-sensitized. used solvent k_d = 4.8 × 10³ s^-1. Added solute (3-15)e-6.