(Z)-Dimethyl 7-[2-(dimethylamino)-2-oxoethyl]-8-ethylidene-7,8-dihydro-3,7,12,17-tetramethylporphine-2,18-dipropionate Singlet oxygen

Schermann, G.; Voelcker, A.; Seikel, K.; Schmidt, R.; Brauer, H.-D.; Montforts, F.-P.
Photochem. Photobiol. 51, 45-51 (1990)

Reaction: (Z)-Dimethyl 7-[2-(dimethylamino)-2-oxoethyl]-8-ethylidene-7,8-dihydro-3,7,12,17-tetramethylporphine-2,18-dipropionate + ¹O₂^* ® products and/or physical quenching
Solvent: CDCl₃

k = 2.7 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: infrared luminescence
Data type: Derived from steady state measurements
Excitation wavelength: 405 nm

Self-sensitized. used solvent k_d = 1.1 × 10² s^-1. [Sensitizer] = 5 × 10^-6 (mol L^-1). [O₂] = air.

Schermann, G.; Voelcker, A.; Seikel, K.; Schmidt, R.; Brauer, H.-D.; Montforts, F.-P.
Photochem. Photobiol. 51, 45-51 (1990)

Reaction: (Z)-Dimethyl 7-[2-(dimethylamino)-2-oxoethyl]-8-ethylidene-7,8-dihydro-3,7,12,17-tetramethylporphine-2,18-dipropionate + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 3.2 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: infrared luminescence
Data type: Derived from steady state measurements
Excitation wavelength: 405 nm

Self-sensitized. used solvent k_d = 4.8 × 10³ s^-1. [Sensitizer] = 5 × 10^-6 (mol L^-1). [O₂] = air.