Mesoporphyrin IX, dimethyl ester Singlet oxygen

Aveline, B.; Delgado, O.; Brault, D.
J. Chem. Soc., Faraday Trans. 88, 1971-1976 (1992)

Reaction: Mesoporphyrin IX, dimethyl ester + ¹O₂^* ® products and/or physical quenching
Solvent: N,N-Dimethylformamide-d₇

k = 1.0 × 10⁷(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Self-sensitized.

Aveline, B.; Delgado, O.; Brault, D.
J. Chem. Soc., Faraday Trans. 88, 1971-1976 (1992)

Reaction: Mesoporphyrin IX, dimethyl ester + ¹O₂^* ® products and/or physical quenching
Solvent: N,N-Dimethylacetamide-d₉

k = 1.4 × 10⁷(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Self-sensitized.

Nonell, S.; Sese, M.L.; Martire, D.O.; Braslavsky, S.E.; Trull, F.R.
Photochem. Photobiol. 53, 185-193 (1991)

Reaction: Mesoporphyrin IX, dimethyl ester + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂Cl₂

k = 1.4 × 10⁷(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly
Excitation wavelength: 666 nm

Photosensitizer = Zinc(II) phthalocyaninebis(pyridine).

Ogilby, P.R.; Foote, C.S.
J. Am. Chem. Soc. 105, 3423-3430 (1983)

Reaction: Mesoporphyrin IX, dimethyl ester + ¹O₂^* ® products and/or physical quenching
Solvent: CD₃CN

k = 2.2 × 10⁷(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Self-sensitized.

Ogilby, P.R.; Foote, C.S.
J. Am. Chem. Soc. 105, 3423-3430 (1983)

Reaction: Mesoporphyrin IX, dimethyl ester + ¹O₂^* ® products and/or physical quenching
Solvent: (CD₃)₂CO

k = 1 × 10⁷(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Self-sensitized.

Ogilby, P.R.; Foote, C.S.
J. Am. Chem. Soc. 105, 3423-3430 (1983)

Reaction: Mesoporphyrin IX, dimethyl ester + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CN

k = 2.5 × 10⁷(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Self-sensitized.

Ogilby, P.R.; Foote, C.S.
J. Am. Chem. Soc. 105, 3423-3430 (1983)

Reaction: Mesoporphyrin IX, dimethyl ester + ¹O₂^* ® products and/or physical quenching
Solvent: (CH₃)₂CO

k = 4 × 10⁷(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Self-sensitized.

Krasnovsky, A.A.,Jr.; Venediktov, E.A.; Cherenko, O.M.
Biophysics (Engl. Transl.) 27, 1009-1016 (1982)

Reaction: Mesoporphyrin IX, dimethyl ester + ¹O₂^* ® products
Solvent: CCl₄

k_react = 400(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = TPP, TPBC or MP; Actinometer = Tetracene.

Krasnovsky, A.A.,Jr.
Photochem. Photobiol. 29, 29-36 (1979)

Reaction: Mesoporphyrin IX, dimethyl ester + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

k = 3 × 10⁶(L mol^-1 s^-1)

Experimental method: Modulated photolysis
Analytical method: infrared luminescence
Data type: Derived from steady state measurements

Photosensitizer = PP, Ph a or BChl a. used solvent k_d = 36 s^-1.

Krasnovsky, A.A.,Jr.; Venediktov, E.A.
Biophysics 23, 294-296 (1978)

Reaction: Mesoporphyrin IX, dimethyl ester + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

k = 2 × 10⁶(L mol^-1 s^-1)

Experimental method: Modulated photolysis
Analytical method: infrared luminescence
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetraphenylporphine. used solvent k_d = 36 s^-1.