Zinc(II) tetraphenylchlorin Singlet oxygen

Venediktov, E.A.; Mozhzhukhin, V.V.; Lipatov, N.G.; Berezin, B.D.
Kinet. Catal. 27, 847-850 (1986)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: py

k = 6 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 743 nm

Photosensitizer = trans-Tetraphenylbacteriochlorin; used solvent k_d = 6.25 × 10⁴ s^-1. [Sensitizer] = 5.0 × 10^-6 (mol L^-1).

Venediktov, E.A.; Mozhzhukhin, V.V.; Lipatov, N.G.; Berezin, B.D.
Kinet. Catal. 27, 847-850 (1986)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: py

k_react = <1.0 × 10⁵(L mol^-1 s^-1), k_reference = 7 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: 743 nm

Photosensitizer = trans-Tetraphenylbacteriochlorin. [Sensitizer] = 5.0 × 10^-6 (mol L^-1).

Venediktov, E.A.; Mozhzhukhin, V.V.; Lipatov, N.G.; Berezin, B.D.
Kinet. Catal. 27, 847-850 (1986)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: C₆H₆

k_react = 2.5 × 10⁷(L mol^-1 s^-1), k_reference = 7 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: 741 nm

Photosensitizer = trans-Tetraphenylbacteriochlorin. [Sensitizer] = 5.0 × 10^-6 (mol L^-1).

Venediktov, E.A.; Mozhzhukhin, V.V.; Lipatov, N.G.; Berezin, B.D.
Kinet. Catal. 27, 847-850 (1986)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: C₆H₆

k = 6 × 10⁹(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 741 nm

Photosensitizer = trans-Tetraphenylbacteriochlorin; used solvent k_d = 3.3 × 10⁴ s^-1. [Sensitizer] = 5.0 × 10^-6 (mol L^-1).

Venediktov, E.A.; Mozhzhukhin, V.V.; Lipatov, N.G.; Berezin, B.D.
Kinet. Catal. 27, 847-850 (1986)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: CCl₄

k = 4 × 10⁹(L mol^-1 s^-1), k_react = 2.0 × 10⁸(L mol^-1 s^-1), k_reference = 7 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = trans-Tetraphenylbacteriochlorin. [Sensitizer] = 5.0 × 10^-6 (mol L^-1).

Venediktov, E.A.; Mozhzhukhin, V.V.; Lipatov, N.G.; Berezin, B.D.
Kinet. Catal. 27, 847-850 (1986)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: CCl₄

k = 4 × 10⁹(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = trans-Tetraphenylbacteriochlorin. used solvent k_d = 36 s^-1. [Sensitizer] = 5.0 × 10^-6 (mol L^-1).

Venediktov, E.A.; Mozhzhukhin, V.V.; Lipatov, N.G.; Berezin, B.D.
Kinet. Catal. 27, 847-850 (1986)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: CH₃COCH₃

k_react = 8.0 × 10⁵(L mol^-1 s^-1), k_reference = 7 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method
Excitation wavelength: 737 nm

Photosensitizer = trans-Tetraphenylbacteriochlorin. [Sensitizer] = 5.0 × 10^-6 (mol L^-1).

Venediktov, E.A.; Mozhzhukhin, V.V.; Lipatov, N.G.; Berezin, B.D.
Kinet. Catal. 27, 847-850 (1986)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: CH₃COCH₃

k = 1 × 10⁹(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 737 nm

Photosensitizer = trans-Tetraphenylbacteriochlorin. used solvent k_d = 36 s^-1. [Sensitizer] = 5.0 × 10^-6 (mol L^-1).

Krasnovsky, A.A.,Jr.; Venediktov, E.A.; Cherenko, O.M.
Biophysics (Engl. Transl.) 27, 1009-1016 (1982)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products
Solvent: CCl₄

k_react = 2 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = TPP, TPBC or MP; Actinometer = Tetracene.

Krasnovsky, A.A.,Jr.
Photochem. Photobiol. 29, 29-36 (1979)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products
Solvent: CCl₄

k_react = 2 × 10⁸(L mol^-1 s^-1), k_reference = 5 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = PP, Ph a or BChl a; Actinometer = Tetracene.

Krasnovsky, A.A.,Jr.
Photochem. Photobiol. 29, 29-36 (1979)

Krasnovsky, A.A.,Jr.; Venediktov, E.A.
Biophysics 23, 294-296 (1978)

Reaction: Zinc(II) tetraphenylchlorin + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

k = 4 × 10⁹(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: infrared luminescence
Data type: Derived from steady state measurements

Photosensitizer = PP, TPP, Ph a or BChl a. used solvent k_d = 36 s^-1.