9-Acetyl-2,3,4,9-tetrahydrocarbazole Singlet oxygen

Saito, I.; Matsugo, S.; Matsuura, T.
J. Am. Chem. Soc. 101, 7332-7338 (1979)

Reaction: 9-Acetyl-2,3,4,9-tetrahydrocarbazole + ¹O₂^* ® products
Reference Reaction: 9-Methyl-2,3,4,9-tetrahydrocarbazole + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 1.7 × 10^-2
T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; meas. k/k_ref = 0.017.

Saito, I.; Matsugo, S.; Matsuura, T.
J. Am. Chem. Soc. 101, 7332-7338 (1979)

Reaction: 9-Acetyl-2,3,4,9-tetrahydrocarbazole + ¹O₂^* ® products
Reference Reaction: 9-Methyl-6-nitro-2,3,4,9-tetrahydrocarbazole + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 2.1 × 10^-1
T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; meas. k/k_ref = 0.021.

Saito, I.; Matsugo, S.; Matsuura, T.
J. Am. Chem. Soc. 101, 7332-7338 (1979)

Reaction: 9-Acetyl-2,3,4,9-tetrahydrocarbazole + ¹O₂^* ® products
Reference Reaction: 1,3-Dimethylindole + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 8.0 × 10^-2
T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; meas. k/k_ref = 0.080.

Saito, I.; Matsugo, S.; Matsuura, T.
J. Am. Chem. Soc. 101, 7332-7338 (1979)

Reaction: 9-Acetyl-2,3,4,9-tetrahydrocarbazole + ¹O₂^* ® products
Reference Reaction: 5-Methoxy-1,2,3-trimethylindole + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 1.0 × 10^-2
T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; meas. k/k_ref = 0.010.

Saito, I.; Matsugo, S.; Matsuura, T.
J. Am. Chem. Soc. 101, 7332-7338 (1979)

Reaction: 9-Acetyl-2,3,4,9-tetrahydrocarbazole + ¹O₂^* ® products
Reference Reaction: 1,2,3-Trimethylindole + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 1 × 10^-2
T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; meas. k/k_ref = 0.01.

Saito, I.; Matsugo, S.; Matsuura, T.
J. Am. Chem. Soc. 101, 7332-7338 (1979)

Reaction: 9-Acetyl-2,3,4,9-tetrahydrocarbazole + ¹O₂^* ® products
Reference Reaction: Indole, 1,2,3-trimethyl-5-nitro- + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 2.0 × 10^-1
T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; meas. k/k_ref = 0.020.