2,5-Dimethylpyrrole Singlet oxygen

Koch, E.
Tetrahedron 24, 6295-6318 (1968)

Reaction: 2,5-Dimethylpyrrole + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

Activation energy = 7.1(kJ mol^-1)
b = 1.6 × 10^-1(mol L^-1), T = 293K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion. meas. k_d/k = 0.16 mol/L.