Pyrrole Singlet oxygen

Venediktov, E.A.; Titova, Yu.V.
Biofizika 38, 1031-1034 (1993)

Reaction: Pyrrole + ¹O₂^* ® products and/or physical quenching
Solvent: py

k = 1.4 × 10⁹(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Anthracene.

Venediktov, E.A.; Titova, Yu.V.
Biofizika 38, 1031-1034 (1993)

Reaction: Pyrrole + ¹O₂^* ® products and/or physical quenching
Solvent: o-Xylene

k = 1.8 × 10⁸(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Anthracene.

Venediktov, E.A.; Titova, Yu.V.
Biofizika 38, 1031-1034 (1993)

Reaction: Pyrrole + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅CH₃

k = 1.7 × 10⁸(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Anthracene.

Venediktov, E.A.; Titova, Yu.V.
Biofizika 38, 1031-1034 (1993)

Reaction: Pyrrole + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅CN

k = 2.1 × 10⁸(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Anthracene.

Venediktov, E.A.; Titova, Yu.V.
Biofizika 38, 1031-1034 (1993)

Reaction: Pyrrole + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

k = 1.5 × 10⁸(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Anthracene.

Venediktov, E.A.; Titova, Yu.V.
Biofizika 38, 1031-1034 (1993)

Reaction: Pyrrole + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃COCH₃

k = 5.4 × 10⁸(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Anthracene.

Venediktov, E.A.; Balakina, T.A.; Berezin, B.D.
Kinet. Catal. 27, 1274-1276 (1986)

Reaction: Pyrrole + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: py

k = 2 × 10⁸(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Excitation wavelength: 737-743 nm

Photosensitizer = trans-Tetraphenylbacteriochlorin; used solvent k_d = 6.25 × 10⁴ s^-1; Indicator = Tetracene, k for indicator = 7 × 10⁶ L/(mol·s). [Sensitizer] = 5.0 × 10^-6 (mol L^-1).

Venediktov, E.A.; Balakina, T.A.; Berezin, B.D.
Kinet. Catal. 27, 1274-1276 (1986)

Reaction: Pyrrole + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: C₆H₆

k = <1.0 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Excitation wavelength: 737-743 nm

Photosensitizer = trans-Tetraphenylbacteriochlorin; used solvent k_d = 3.3 × 10⁴ s^-1; Indicator = Tetracene, k for indicator = 7 × 10⁶ L/(mol·s). [Sensitizer] = 5.0 × 10^-6 (mol L^-1).

Venediktov, E.A.; Balakina, T.A.; Berezin, B.D.
Kinet. Catal. 27, 1274-1276 (1986)

Reaction: Pyrrole + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Tetracene + ¹O₂^* ®
Solvent: CH₃COCH₃

k = 6 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Excitation wavelength: 737-743 nm

Photosensitizer = trans-Tetraphenylbacteriochlorin; used solvent k_d = 2.0 × 10⁴ s^-1; Indicator = Tetracene, k for indicator = 7 × 10⁶ L/(mol·s). [Sensitizer] = 5.0 × 10^-6 (mol L^-1).