2,5-Diphenyl-4-methyloxazole Singlet oxygen

Wasserman, H.H.; Pickett, J.E.; Vinnick, F.S.
Heterocycles 15, 1069-1073 (1981)

Reaction: 2,5-Diphenyl-4-methyloxazole + ¹O₂^* ® products and/or physical quenching
Solvent: Benzene

k = 3.9 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Derived from steady state measurements

used solvent k_d = 8.0 × 10⁴ s^-1.

Wasserman, H.H.; Pickett, J.E.; Vinnick, F.S.
Heterocycles 15, 1069-1073 (1981)

Reaction: 2,5-Diphenyl-4-methyloxazole + ¹O₂^* ® products and/or physical quenching
Solvent: 1-Pentanol

b = 3.0 × 10^-3(mol L^-1)

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Derived from steady state measurements

meas. k_d/k = 0.003 mol/L.

Wasserman, H.H.; Pickett, J.E.; Vinnick, F.S.
Heterocycles 15, 1069-1073 (1981)

Reaction: 2,5-Diphenyl-4-methyloxazole + ¹O₂^* ® products and/or physical quenching
Solvent: Dimethyl sulfoxide

b = 1.5 × 10^-3(mol L^-1)

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Derived from steady state measurements

meas. k_d/k = 0.0015 mol/L.

Wasserman, H.H.; Pickett, J.E.; Vinnick, F.S.
Heterocycles 15, 1069-1073 (1981)

Reaction: 2,5-Diphenyl-4-methyloxazole + ¹O₂^* ® products and/or physical quenching
Solvent: Ethanol

k = 3.3 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Derived from steady state measurements

used solvent k_d = 1.5 × 10⁵ s^-1.

Wasserman, H.H.; Pickett, J.E.; Vinnick, F.S.
Heterocycles 15, 1069-1073 (1981)

Reaction: 2,5-Diphenyl-4-methyloxazole + ¹O₂^* ® products and/or physical quenching
Solvent: Methanol

k = 3.5 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Derived from steady state measurements

used solvent k_d = 2.0 × 10⁵ s^-1.

Wasserman, H.H.; Pickett, J.E.; Vinnick, F.S.
Heterocycles 15, 1069-1073 (1981)

Reaction: 2,5-Diphenyl-4-methyloxazole + ¹O₂^* ® products and/or physical quenching
Solvent: Dioxane

k = 1.6 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Derived from steady state measurements

used solvent k_d = 2.9 × 10⁴ s^-1.