Furfuryl alcohol Singlet oxygen

El Bouamri, M.; Gorrichon, J.P.; Braun, A.M.; Oliveros, E.
Photochem. Photobiol. 54, 619-623 (1991)

Reaction: Furfuryl alcohol + ¹O₂^* ® products
Solvent: CD₃OD

k_react = 3.0 × 10⁷(L mol^-1 s^-1), T = 295K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements
Excitation wavelength: 546 nm

Photosensitizer = Rose Bengal dianion. used solvent k_d = 4.0 × 10³ s^-1.

Gottfried, V.; Kimel, S.
J. Photochem. Photobiol., B 8, 419-430 (1991)

Reaction: Furfuryl alcohol + ¹O₂^* ® products
Solvent: H₂O

Activation energy = 23(kJ mol^-1), Log(A) = 12.114, Temperature range 288 to 318 K
k_react = 1.4 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetrakis(4-sulfonatophenyl)porphine; used solvent k_d = 2.5 × 10⁵ s^-1; phosphate buffer contg. 1.6% NaCl.

Murasecco, P.; Oliveros, E.; Braun, A.M.; Monnier, P.
Photobiochem. Photobiophys. 9, 193-201 (1985)

Reaction: Furfuryl alcohol + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O

b = 3.0 × 10^-3(mol L^-1), T = 295K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements
Excitation wavelength: 405 nm

Photosensitizer = Hematoporphyrin derivative; soln. contg. 0.9% NaCl. meas. k_d/k = 3.0 × 10^-3 mol/L. [Sensitizer] = 10^-4 (mol L^-1).

Haag, W.R.; Hoigne, J.; Gassman, E.; Braun, A.M.
Chemosphere 13, 631-640 (1984)

Reaction: Furfuryl alcohol + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O

k = 1.2 × 10⁸(L mol^-1 s^-1), b = 2.3 × 10^-3(mol L^-1), T = 295K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; used solvent k_d = 2.5 × 10⁵ s^-1; same k at pH 7, 10, 11.5 [87SCU/HOI].

Young, R.H.; Martin, R.L.; Chinh, N.; Mallon, C.; Kayser, R.H.
Can. J. Chem. 50, 932-938 (1972)

Reaction: Furfuryl alcohol + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

b = 4.7 × 10^-3(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements using indicator

Photosensitizer = Methylene Blue; Indicator = 1,3-Diphenylisobenzofuran. meas. k_d/k = 4.7 × 10^-3 mol/L.

Koch, E.
Tetrahedron 24, 6295-6318 (1968)

Reaction: Furfuryl alcohol + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

Activation energy = 2.9(kJ mol^-1)
b = 3.3 × 10^-3(mol L^-1), T = 293K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion. meas. k_d/k = 3.3 × 10^-3 mol/L.

Sluyterman, L.A.E.
Recl. Trav. Chim. Pays-Bas 80, 989-1002 (1961)

Reaction: Furfuryl alcohol + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O

pH range 3.0 to 8.0
b = 1.8 × 10^-3(mol L^-1), T = 310K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = 3,6-Diaminoacridine. meas. k_d/k = 1.8 × 10^-3 mol/L.