4-Acetoxymethyl-2-(phenylmethyl)furan Singlet oxygen

Clements, P.; Wells, C.H.J.
Pestic. Sci. 35, 305-308 (1992)

Reaction: 4-Acetoxymethyl-2-(phenylmethyl)furan + ¹O₂^* ® products and/or physical quenching
Solvent: Methanol

Activation energy = ~0(kJ mol^-1), Log(A) = 7.803, Entropy of activation = 0.0(J K^-1 mol^-1), Temperature range 293 to 308 K
k = 6.3 × 10⁷(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; k_d not given.

Clements, P.; Wells, C.H.J.
Pestic. Sci. 35, 305-308 (1992)

Reaction: 4-Acetoxymethyl-2-(phenylmethyl)furan + ¹O₂^* ® products and/or physical quenching
Solvent: Methanol, 50%, Water, 50%

Activation energy = ~0(kJ mol^-1), Log(A) = 8.916, Entropy of activation = 0.0(J K^-1 mol^-1), Temperature range 293 to 308 K
k = 8.2 × 10⁸(L mol^-1 s^-1), T = 298K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; k_d not given.