2,3-Dihydro-5-methylfuran Singlet oxygen

Gollnick, K.; Knutzen-Mies, K.
J. Org. Chem. 56, 4017-4027 (1991)

Reaction: 2,3-Dihydro-5-methylfuran + ¹O₂^* ® products
Solvent: C₆H₆

k_react = 1.5 × 10⁷(L mol^-1 s^-1), b = 2.9 × 10^-3(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal or Tetraphenylporphine; Actinometer = 2,5-Dimethylfuran; used solvent k_d = 4.2 × 10⁴ s^-1; Rate of physical quenching/product formation = £ 0.1; 52% [2+2] cycloaddition. [Sensitizer] = 2-10 × 10^-4 (mol L^-1). [Indicator] = 8-40 × 10^-3 (mol L^-1).

Gollnick, K.; Knutzen-Mies, K.
J. Org. Chem. 56, 4017-4027 (1991)

Reaction: 2,3-Dihydro-5-methylfuran + ¹O₂^* ® products
Solvent: CH₃CN

k_react = 3.4 × 10⁷(L mol^-1 s^-1), b = 9.7 × 10^-4(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; used solvent k_d = 3.3 × 10⁴ s^-1; Actinometer = 2,5-Dimethylfuran; Rate of physical quenching/product formation = £ 0.1; 85% [2+2] cycloaddition. [Sensitizer] = 2-10 × 10^-4 (mol L^-1). [Indicator] = 8-40 × 10^-3 (mol L^-1).

Gollnick, K.; Knutzen-Mies, K.
J. Org. Chem. 56, 4017-4027 (1991)

Reaction: 2,3-Dihydro-5-methylfuran + ¹O₂^* ® products
Solvent: CH₃COCH₃

k_react = 2.8 × 10⁷(L mol^-1 s^-1), b = 1.4 × 10^-3(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; used solvent k_d = 3.8 × 10⁴ s^-1; Actinometer = 2,5-Dimethylfuran; Rate of physical quenching/product formation = £ 0.1; 78% [2+2] cycloaddition. [Sensitizer] = 2-10 × 10^-4 (mol L^-1). [Indicator] = 8-40 × 10^-3 (mol L^-1).

Gollnick, K.; Knutzen-Mies, K.
J. Org. Chem. 56, 4017-4027 (1991)

Reaction: 2,3-Dihydro-5-methylfuran + ¹O₂^* ® products
Solvent: MeOH

k_react = 1.4 × 10⁷(L mol^-1 s^-1), b = 1.0 × 10^-2(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; used solvent k_d = 1.4 × 10⁵ s^-1; Actinometer = 2,5-Dimethylfuran; Rate of physical quenching/product formation = £ 0.1. [Sensitizer] = 2-10 × 10^-4 (mol L^-1). [Indicator] = 8-40 × 10^-3 (mol L^-1).