2-tert-Butylfuran Singlet oxygen

Clennan, E.L.; Mehrsheikh-Mohammadi, M.E.
J. Am. Chem. Soc. 106, 7112-7118 (1984)

Reaction: 2-tert-Butylfuran + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂Cl₂

k = 6.1 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1 × 10⁴ s^-1; k for indicator = 3.3 × 10⁷ L/(mol·s).

Clennan, E.L.; Mehrsheikh-Mohammadi, M.E.
J. Am. Chem. Soc. 106, 7112-7118 (1984)

Reaction: 2-tert-Butylfuran + ¹O₂^* ® products and/or physical quenching
Solvent: CH₂Cl₂

k = 6.4 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Mesoporphyrin IX, dimethyl ester; used solvent k_d = 1 × 10⁴ s^-1; Indicator = 1,3-Diphenylisobenzofuran.