2,5-Bis(hydroxymethyl)furan Singlet oxygen

Richard, C.; Martre, A.M.; Boule, P.
J. Photochem. Photobiol., A 66, 225-234 (1992)

Reaction: 2,5-Bis(hydroxymethyl)furan + ¹O₂^* ® products and/or physical quenching
Solvent: H₂O

b = 4.0 × 10^-3(mol L^-1), pH = 7

Experimental method: Photolysis
Analytical method: HPLC
Data type: Derived from steady state measurements
Excitation wavelength: 546 nm

Photosensitizer = Rose Bengal dianion. meas. k_d/k = 4.0 × 10^-3 mol/L.

Cottier, L.; Descotes, G.; Nigay, H.; Parron, J.-C.; Gregoire, V.
Bull. Soc. Chim. Fr., 844-850 (1986)

Reaction: 2,5-Bis(hydroxymethyl)furan + ¹O₂^* ® products
Reference Reaction: Furfuryl alcohol + ¹O₂^* ®
Solvent: CH₃CH₂OH

k/k_reference = 1.2
T = 293K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion. Meas. k/k_ref = 1.2.