8-tert-Butyl-5-methyltocol Singlet oxygen

Mukai, K.; Daifuku, K.; Okabe, K.; Tanigaki, T.; Inoue, K.
J. Org. Chem. 56, 4188-4192 (1991)

Reaction: 8-tert-Butyl-5-methyltocol + ¹O₂^* ® products and/or physical quenching
Solvent: EtOH

k = 1.6 × 10⁸(L mol^-1 s^-1), T = 308K

Experimental method: Chemical reaction
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = 1,3-Diphenylisobenzofuran; used solvent k_d = 8.3 × 10⁴ s^-1; ¹O₂* from MNPO₂. [Indicator] = 4.3 × 10^-5 (mol L^-1).