1,4-Dimethoxy-9,10-diphenylanthracene
Singlet oxygen


Ogilby, P.R.; Kristiansen, M.; Martire, D.O.; Scurlock, R.D.; Taylor, V.L.; Clough, R.L.
Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 34, 133-134 (1993)

Reaction: 1,4-Dimethoxy-9,10-diphenylanthracene + 1O2* ® products and/or physical quenching
Solvent: Toluene

k = 1.3 × 108(L mol-1 s-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Self-sensitized;


Brauer, H.-D.; Acs, A.; Drews, W.; Gabriel, R.; Ghaeni, S.; Schmidt, R.
J. Photochem. 25, 475-488 (1984)

Reaction: 1,4-Dimethoxy-9,10-diphenylanthracene + 1O2* ® products and/or physical quenching
Solvent: Et2O

b = 2 × 10-4(mol L-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; meas. kd/k = 0.0002 mol/L.


Brauer, H.-D.; Acs, A.; Drews, W.; Gabriel, R.; Ghaeni, S.; Schmidt, R.
J. Photochem. 25, 475-488 (1984)

Reaction: 1,4-Dimethoxy-9,10-diphenylanthracene + 1O2* ® products and/or physical quenching
Solvent: Ethyl acetate

b = 9.3 × 10-5(mol L-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; meas. kd/k = 0.000093 mol/L.


Monroe, B.M.
J. Phys. Chem. 82, 15-18 (1978)

Reaction: 1,4-Dimethoxy-9,10-diphenylanthracene + 1O2* ® products and/or physical quenching
Solvent: CHCl3

k = 3.2 × 108(L mol-1 s-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent kd = 1.7 × 104 s-1; k for indicator = 5.3 × 107 L/(mol·s).


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