Anthracene Singlet oxygen

Nowakowska, M.
Makromol. Chem. 181, 1013-1020 (1980)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: Hexane

k = 3 × 10⁵(L mol^-1 s^-1), k_reference = 3 × 10¹⁰(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Excitation wavelength: 365 nm

Self-sensitized; Indicator = b-Carotene; used solvent k_d = 3 × 10⁵ s^-1. Use b-Carotene as quencher.

Nowakowska, M.; Kowal, J.
Eur. Polym. J. 16, 615-618 (1980)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

k = 3.5 × 10⁵(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; used solvent k_d = 1.4 × 10³ s^-1.

Monroe, B.M.
J. Phys. Chem. 82, 15-18 (1978)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 5.4 × 10⁵(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).

Stevens, B.; Perez, S.R.; Ors, J.A.
J. Am. Chem. Soc. 96, 6846-6850 (1974)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Reference Reaction: Rub + ¹O₂^* ®
Solvent: C₆H₆

k = 1.6 × 10⁵(L mol^-1 s^-1), b = 2.7 × 10^-1(mol L^-1), b_ref = 1.0 × 10^-3(mol L^-1), T = 298K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Photosensitizer = Rubrene; meas. k_d/k = 0.27 mol/L, used solvent k_d = 4.2 × 10⁴ s^-1.

Foote, C.; Peterson, E.R.; Lee, K.-W.
J. Am. Chem. Soc. 94, 1032-1033 (1972)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

b = 4.7 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Diacenaphtho[1,2-b:2',1'-d]thiophene. meas. k_d/k = 0.047 mol/L.

Foote, C.; Peterson, E.R.; Lee, K.-W.
J. Am. Chem. Soc. 94, 1032-1033 (1972)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂

b = 2.6 × 10^-3(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Diacenaphtho[1,2-b:2',1'-d]thiophene. meas. k_d/k = 0.0026 mol/L.

Foote, C.; Peterson, E.R.; Lee, K.-W.
J. Am. Chem. Soc. 94, 1032-1033 (1972)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂, 96%, C₆H₆, 4%

b = 2.7 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Diacenaphtho[1,2-b:2',1'-d]thiophene; solvent in mole %. meas. k_d/k = 0.027 mol/L.

Foote, C.; Peterson, E.R.; Lee, K.-W.
J. Am. Chem. Soc. 94, 1032-1033 (1972)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂, 93%, C₆H₆, 7%

b = 5.2 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = Diacenaphtho[1,2-b:2',1'-d]thiophene; solvent in mole %. meas. k_d/k = 0.052 mol/L.

Foote, C.; Peterson, E.R.; Lee, K.-W.
J. Am. Chem. Soc. 94, 1032-1033 (1972)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂, 75%, C₆H₆, 25%

b = 9.4 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetraphenylporphine; solvent in mole %. meas. k_d/k = 0.094 mol/L.

Foote, C.; Peterson, E.R.; Lee, K.-W.
J. Am. Chem. Soc. 94, 1032-1033 (1972)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂, 50%, C₆H₆, 50%

b = 7.7 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetraphenylporphine; solvent in mole %. meas. k_d/k = 0.77 mol/L.

Livingston, R.; Rao, V.S.
J. Phys. Chem. 63, 794-799 (1959)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅Br

b = 1.2 × 10^-1(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 0.12 mol/L.

Livingston, R.; Rao, V.S.
J. Phys. Chem. 63, 794-799 (1959)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

b = 5.7 × 10^-1(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 0.57 mol/L.

Bowen, E.J.; Tanner, D.W.
Trans. Faraday Soc. 51, 475-481 (1955)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

Temperature range 263 to 317 K
b = 4.2 × 10^-1(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 0.42 mol/L.

Bowen, E.J.; Tanner, D.W.
Trans. Faraday Soc. 51, 475-481 (1955)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

Temperature range 263 to 317 K
b = 3.6 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 0.036 mol/L.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

b = 4.0 × 10^-3(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 0.004 mol/L.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

b = 1.4 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 0.14 mol/L.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂

b = 3.6 × 10^-3(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 0.0036 mol/L.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂, 99%, C₆H₆, 1%

b = 1.5 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; meas. k_d/k = 0.015 mol/L; solvent in mole %.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂, 95%, C₆H₆, 5%

b = 3.8 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; solvent in mole %. meas. k_d/k = 0.038 mol/L.

Bowen, E.J.
Discuss. Faraday Soc., 143-146 (1953)

Reaction: Anthracene + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂, 90%, C₆H₆, 10%

b = 6.2 × 10^-2(mol L^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Self-sensitized; solvent in mole %. meas. k_d/k = 0.062 mol/L.