9,9'-Bifluorenylidene Singlet oxygen

Richardson, W.H.; Hodge, V.
J. Org. Chem. 35, 1216-1217 (1970)

Reaction: 9,9'-Bifluorenylidene + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: CH₂Cl₂

k/k_reference = 3.4 × 10^-2

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = MB. meas. k/k_ref = 0.034.

Richardson, W.H.; Hodge, V.
J. Org. Chem. 35, 1216-1217 (1970)

Reaction: 9,9'-Bifluorenylidene + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: dioxane, 80%, MeOH, 20%

k/k_reference = 3.4 × 10^-2

Experimental method: Chemical reaction
Analytical method: GLC
Data type: Relative value measured by steady state method

meas. k/k_ref = 0.034; ¹O₂* from H₂O₂/NaOCl.