Anisole Singlet oxygen

Corey, E.J.; Khan, A.U.; Ha, D.-C.
Tetrahedron Lett. 31, 1389-1392 (1990)

Reaction: C₆H₅OCH₃ + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

k = 2.0 × 10⁵(L mol^-1 s^-1), T = 296K

Experimental method: Chemical reaction
Analytical method: infrared luminescence
Data type: Derived from steady state measurements

used solvent k_d = 1.7 × 10³ s^-1; ¹O₂* from DMNO₂.

Palumbo, M.C.; Garcia, N.A.
Toxicol. Environ. Chem. 17, 103-116 (1988)

Reaction: C₆H₅OCH₃ + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆, 60%, MeOH, 40%

k = <10⁴(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Limiting value

Photosensitizer = Indicator = Rubrene; soln. cont. 6 × 10^-3 mol L^-1 KOH.

Saito, I.; Imuta, M.; Matsuura, T.
Tetrahedron 28, 5307-5311 (1972)

Reaction: C₆H₅OCH₃ + ¹O₂^* ® products
Reference Reaction: 1,2,4,5-(CH₃O)₄C₆H₂ + ¹O₂^* ®
Solvent: MeOH

k_react £ 5 × 10⁶(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = RB and MB; No measurable effect.