Ethylbenzene Singlet oxygen

Corey, E.J.; Khan, A.U.; Ha, D.-C.
Tetrahedron Lett. 31, 1389-1392 (1990)

Reaction: C₆H₅CH₂CH₃ + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄

k = 1.3 × 10⁵(L mol^-1 s^-1), T = 296K

Experimental method: Chemical reaction
Analytical method: infrared luminescence
Data type: Derived from steady state measurements

used solvent k_d = 1.7 × 10³ s^-1; ¹O₂* from DMNO₂.

Darmanyan, A.P.; Vidoczy, T.; Irinii, G.; Gal, D.
Bull. Acad. Sci. USSR, Div. Chem. Sci. 32, 2423-2429 (1983)

Reaction: C₆H₅CH₂CH₃ + ¹O₂^* ® products and/or physical quenching
Solvent: Carbon tetrachloride, 98%, Methanol, 2%

k = 3.6 × 10³(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly using indicator
Excitation wavelength: 589 nm

Photosensitizer = MB; Indicator = 1,3-Diphenylisobenzofuran.

Bortolus, P.; Dellonte, S.; Beggiato, G.; Corio, W.
Eur. Polym. J. 13, 185-188 (1977)

Reaction: C₆H₅CH₂CH₃ + ¹O₂^* ® products and/or physical quenching
Solvent: CCl₄, 96%, MeOH, 4%

k = 500(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly using indicator
Excitation wavelength: 694 nm

Photosensitizer = MB; Indicator = 1,3-Diphenylisobenzofuran.