Benzvalene Singlet oxygen

Gollnick, K.; Griesbeck, A.
Tetrahedron Lett. 25, 725-728 (1984)

Reaction: Benzvalene + ¹O₂^* ® products
Solvent: C₆H₆

b = 1.1(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetraphenylporphine; Actinometer = 2,5-Dimethylfuran; meas. k_d/k = 1.1 mol/L; meas. 1 + k_q/k_r = 1. [Indicator] = 4 × 10^-2 (mol L^-1).

Gollnick, K.; Griesbeck, A.
Tetrahedron Lett. 25, 725-728 (1984)

Reaction: Benzvalene + ¹O₂^* ® products
Solvent: CCl₄

b = 59(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetraphenylporphine; Actinometer = 2,5-Dimethylfuran; meas. k_d/k = 0.059 mol/L; meas. 1 + k_q/k_r = 1. [Indicator] = 4 × 10^-2 (mol L^-1).

Gollnick, K.; Griesbeck, A.
Tetrahedron Lett. 25, 725-728 (1984)

Reaction: Benzvalene + ¹O₂^* ® products
Solvent: CH₂Cl₂

b = 4.9(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetraphenylporphine; Actinometer = 2,5-Dimethylfuran; meas. k_d/k = 0.0049 mol/L; meas. 1 + k_q/k_r = 1. [Indicator] = 4 × 10^-2 (mol L^-1).

Gollnick, K.; Griesbeck, A.
Tetrahedron Lett. 25, 725-728 (1984)

Reaction: Benzvalene + ¹O₂^* ® products
Solvent: CH₃CN

b = 4.0(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; Actinometer = 2,5-Dimethylfuran; meas. k_d/k = 0.0040 mol/L; meas. 1 + k_q/k_r = 1. [Indicator] = 4 × 10^-2 (mol L^-1).

Gollnick, K.; Griesbeck, A.
Tetrahedron Lett. 25, 725-728 (1984)

Reaction: Benzvalene + ¹O₂^* ® products
Solvent: CH₃COCH₃

b = 7.2(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; Actinometer = 2,5-Dimethylfuran; meas. k_d/k = 0.0072 mol/L; meas. 1 + k_q/k_r = 1. [Indicator] = 4 × 10^-2 (mol L^-1).

Gollnick, K.; Griesbeck, A.
Tetrahedron Lett. 25, 725-728 (1984)

Reaction: Benzvalene + ¹O₂^* ® products
Solvent: CHCl₃

b = 20(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetraphenylporphine; Actinometer = 2,5-Dimethylfuran; meas. k_d/k = 0.020 mol/L; meas. 1 + k_q/k_r = 1. [Indicator] = 4 × 10^-2 (mol L^-1).

Gollnick, K.; Griesbeck, A.
Tetrahedron Lett. 25, 725-728 (1984)

Reaction: Benzvalene + ¹O₂^* ® products
Solvent: CH₃OH

b = 19(mol L^-1), T = 286K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion; Actinometer = 2,5-Dimethylfuran; meas. k_d/k = 0.019 mol/L; meas. 1 + k_q/k_r = 1. [Indicator] = 4 × 10^-2 (mol L^-1).