Acetoxymethylideneadamantane Singlet oxygen

Wilson, S.L.; Schuster, G.B.
J. Am. Chem. Soc. 105, 679-681 (1983)

Reaction: Acetoxymethylideneadamantane + ¹O₂^* ® products and/or physical quenching
Solvent: CD₃COCD₃

k = 3.4 × 10⁴(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue.

Wilson, S.L.; Schuster, G.B.
J. Am. Chem. Soc. 105, 679-681 (1983)

Reaction: Acetoxymethylideneadamantane + ¹O₂^* ® products and/or physical quenching
Solvent: CD₃OD

k = 2.1 × 10⁴(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Methylene Blue.