(E)-2,3-Dimethyl-2-butene-d6 Singlet oxygen

Grdina, B.; Orfanopoulos, M.; Stephenson, L.M.
J. Am. Chem. Soc. 101, 3111-3112 (1979)

Reaction: (E)-2,3-Dimethyl-2-butene-d₆ + ¹O₂^* ® products
Reference Reaction: (CH₃)₂C=C(CH₃)₂ + ¹O₂^* ®
Solvent: CD₃COCD₃

k/k_reference = 7.1 × 10^-1
T = 263K

Experimental method: Photolysis
Analytical method: nuclear magnetic resonance
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion. Meas. k/k_ref = 0.71.