2-Benzyl-1,3-butadiene Singlet oxygen

Matsumoto, M.; Kuroda, K.
Synth. Commun. 11, 987-992 (1981)

Reaction: 2-Benzyl-1,3-butadiene + ¹O₂^* ® products and/or physical quenching
Solvent: Benzene

b = 7.3(mol L^-1), T = 277K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetraphenylporphine. meas. k_d/k = 7.3 mol/L.

Matsumoto, M.; Kuroda, K.
Synth. Commun. 11, 987-992 (1981)

Reaction: 2-Benzyl-1,3-butadiene + ¹O₂^* ® products and/or physical quenching
Solvent: Carbon tetrachloride

b = 8.2 × 10^-1(mol L^-1), T = 277K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetraphenylporphine. meas. k_d/k = 0.82 mol/L.

Matsumoto, M.; Kuroda, K.
Synth. Commun. 11, 987-992 (1981)

Reaction: 2-Benzyl-1,3-butadiene + ¹O₂^* ® products and/or physical quenching
Solvent: Methyl ethyl ketone

b = 5.7(mol L^-1), T = 277K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion. meas. k_d/k = 0.57 mol/L.

Matsumoto, M.; Kuroda, K.
Synth. Commun. 11, 987-992 (1981)

Reaction: 2-Benzyl-1,3-butadiene + ¹O₂^* ® products and/or physical quenching
Solvent: Chloroform

b = 3.4(mol L^-1), T = 277K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = 5,10,15,20-Tetraphenylporphine. meas. k_d/k = 3.4 mol/L.

Matsumoto, M.; Kuroda, K.
Synth. Commun. 11, 987-992 (1981)

Reaction: 2-Benzyl-1,3-butadiene + ¹O₂^* ® products and/or physical quenching
Solvent: Ethanol

b = 11(mol L^-1), T = 277K

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements

Photosensitizer = Rose Bengal dianion. meas. k_d/k = 11 mol/L.