Caryophyllene Singlet oxygen

Gollnick, K.; Franken, T.; Schade, G.; Doerhoefer, G.
Ann. N.Y. Acad. Sci. 171, 89-107 (1970)

Reaction: Caryophyllene + ¹O₂^* ® products
Reference Reaction: g-Caryophyllene + ¹O₂^* ®
Solvent: MeOH, 50%, C₆H₆, 50%

k/k_reference = 5.1
T = 293K

Experimental method: Photolysis
Analytical method: VPC
Data type: Relative value measured by steady state method

Photosensitizer = Biphenyl, triphenylene, quinoline, naphthalene, pyrene, Rose Bengal and Methylene Blue. Meas. k/k_ref = 5.1.