7,7-Dimethyl-2-(trimethylsiloxy)norborn-2-ene Singlet oxygen

Jefford, C.W.; Rimbault, C.G.
J. Am. Chem. Soc. 100, 6515-6516 (1978)

Reaction: 7,7-Dimethyl-2-(trimethylsiloxy)norborn-2-ene + ¹O₂^* ® products
Reference Reaction: 7,7-Dimethyl-2-(trimethylsiloxy)-norborna-2,5-diene + ¹O₂^* ®
Solvent: CDCl₃

k/k_reference = 2.4 × 10^-1

Experimental method: Photolysis
Analytical method: nuclear magnetic resonance
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine. Meas. k/k_ref = 0.24.

Jefford, C.W.; Rimbault, C.G.
J. Am. Chem. Soc. 100, 6515-6516 (1978)

Reaction: 7,7-Dimethyl-2-(trimethylsiloxy)norborn-2-ene + ¹O₂^* ® products
Reference Reaction: 2-(Trimethylsiloxy)norborna-2,5-diene + ¹O₂^* ®
Solvent: CDCl₃

k/k_reference = 5.9

Experimental method: Photolysis
Analytical method: nuclear magnetic resonance
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine. Meas. k/k_ref = 5.9.

Jefford, C.W.; Rimbault, C.G.
J. Am. Chem. Soc. 100, 6515-6516 (1978)

Reaction: 7,7-Dimethyl-2-(trimethylsiloxy)norborn-2-ene + ¹O₂^* ® products
Reference Reaction: 2-(Trimethylsiloxy)norborn-2-ene + ¹O₂^* ®
Solvent: CDCl₃

k/k_reference = 1.2 × 10^-1

Experimental method: Photolysis
Analytical method: nuclear magnetic resonance
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine. Meas. k/k_ref = 0.12.