2-Methylenenorbornane Singlet oxygen

Jefford, C.W.; Rimbault, C.G.
J. Org. Chem. 43, 1908-1912 (1978)

Reaction: 2-Methylenenorbornane + ¹O₂^* ® products
Reference Reaction: 5-Methylene-2-norbornene + ¹O₂^* ®
Solvent: CH₃CN

k/k_reference = 4.3
T = 273K

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Meas. k/k_ref = 4.3.

Jefford, C.W.; Rimbault, C.G.
J. Org. Chem. 43, 1908-1912 (1978)

Reaction: 2-Methylenenorbornane + ¹O₂^* ® products
Reference Reaction: 2,7,7-Trimethylnorborn-2-ene + ¹O₂^* ®
Solvent: CH₃CN

k/k_reference = 13
T = 273K

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Meas. k/k_ref = 13.

Jefford, C.W.; Boschung, A.F.
Helv. Chim. Acta 57, 2242-2257 (1974)

Reaction: 2-Methylenenorbornane + ¹O₂^* ® products
Reference Reaction: 7,7-Dimethyl-2-methylenenorbornane + ¹O₂^* ®
Solvent: CH₃CN

k/k_reference = 3.8

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Meas. k/k_ref = 3.8.

Jefford, C.W.; Boschung, A.F.
Helv. Chim. Acta 57, 2242-2257 (1974)

Reaction: 2-Methylenenorbornane + ¹O₂^* ® products
Reference Reaction: endo-2-Methylenenorbornane-3-d + ¹O₂^* ®
Solvent: CH₃CN

k/k_reference = 9.8 × 10^-1

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Meas. k/k_ref = 0.98.

Jefford, C.W.; Boschung, A.F.
Helv. Chim. Acta 57, 2242-2257 (1974)

Reaction: 2-Methylenenorbornane + ¹O₂^* ® products
Reference Reaction: exo-2-Methylenenorbornane-3-d + ¹O₂^* ®
Solvent: CH₃CN

k/k_reference = 8.8 × 10^-1

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Meas. k/k_ref = 0.88.

Jefford, C.W.; Boschung, A.F.
Helv. Chim. Acta 57, 2242-2257 (1974)

Reaction: 2-Methylenenorbornane + ¹O₂^* ® products
Reference Reaction: 2-Methylnorborn-2-ene + ¹O₂^* ®
Solvent: CH₃CN

k/k_reference = 3.2 × 10^-1

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Meas. k/k_ref = 0.32.

Jefford, C.W.; Boschung, A.F.
Helv. Chim. Acta 57, 2242-2257 (1974)

Reaction: 2-Methylenenorbornane + ¹O₂^* ® products
Reference Reaction: 2,7,7-Trimethylnorborn-2-ene + ¹O₂^* ®
Solvent: CH₃CN

k/k_reference = 13

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Meas. k/k_ref = 13.

Jefford, C.W.; Boschung, A.F.; Moriarty, R.M.; Rimbault, C.G.; Laffer, M.H.
Helv. Chim. Acta 56, 2649-2659 (1973)

Reaction: 2-Methylenenorbornane + ¹O₂^* ® products and/or physical quenching
Reference Reaction: c-C₆H₉CH₃ + ¹O₂^* ®
Solvent: CH₃CN

k/k_reference = 6.5 × 10^-2
T ~284K

Experimental method: Photolysis
Analytical method: GLC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; Meas. k/k_ref = 0.065.