exo,exo-2,3-Dioxymethyl-7-adamantylidenenorbornane Singlet oxygen

Shereshovets, V.V.; Kabalnova, N.N.; Komissarov, V.D.; Mavrodiev, V.K.; Lerman, B.M.; Belogaeva, T.A.; Tolstikov, G.A.
React. Kinet. Catal. Lett. 41, 251-256 (1990)

Reaction: exo,exo-2,3-Dioxymethyl-7-adamantylidenenorbornane + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₅Cl, 90%, 2-PrOH, 10%

k = 1.8 × 10⁶(L mol^-1 s^-1), T = 273K

Experimental method: Chemical reaction
Analytical method: infrared luminescence
Data type: Derived from steady state measurements

used solvent k_d = 4.1 × 10⁴ s^-1; ¹O₂* from hydrotrioxide, e.g. (CH₃)₂C(OH)OOOH.