Hexamethyl Coa Cob-dicyano-7-de(carboxymethyl)-7,8-didehydrocobyrinate Singlet oxygen

Kraeutler, B.; Stepanek, R.
Helv. Chim. Acta 66, 1493-1512 (1983)

Reaction: Hexamethyl Coa Cob-dicyano-7-de(carboxymethyl)-7,8-didehydrocobyrinate + ¹O₂^* ® products and/or physical quenching
Solvent: C₆D₆

k = 8.0 × 10⁶(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 710 nm

Self-sensitized; k_d not given. Added solute <4 × 10^-4. [Indicator] = 6.3 × 10^-3 (mol L^-1). [O₂] = O₂.

Kraeutler, B.; Stepanek, R.
Helv. Chim. Acta 66, 1493-1512 (1983)

Reaction: Hexamethyl Coa Cob-dicyano-7-de(carboxymethyl)-7,8-didehydrocobyrinate + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 5 × 10⁶(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 710 nm

Self-sensitized; k_d not given. Added solute <4 × 10^-4. [Indicator] = 6.3 × 10^-3 (mol L^-1). [O₂] = O₂.

Kraeutler, B.; Stepanek, R.
Helv. Chim. Acta 66, 1493-1512 (1983)

Reaction: Hexamethyl Coa Cob-dicyano-7-de(carboxymethyl)-7,8-didehydrocobyrinate + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃OH

k = 6 × 10⁶(L mol^-1 s^-1), T = 293K

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements
Excitation wavelength: 710 nm

Self-sensitized; used solvent k_d = 1 × 10⁵ s^-1. Added solute <4 × 10^-4. [Indicator] = 6.3 × 10^-3 (mol L^-1). [O₂] = O₂.