Acetone azine Singlet oxygen

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 3,4,4,5-Tetramethylpyrazole + ¹O₂^* ®
Solvent: CFCl₃

k/k_reference = 3.1
T = 253K

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine; meas. k/k_ref = 3.1. Added solute 0.2. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 2 × 10^-1 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 3,4,4,5-Tetramethylpyrazole + ¹O₂^* ®
Solvent: CCl₄

k/k_reference = 3.2
T = 253K

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine; meas. k/k_ref = 3.2; with 10^-4 mol L^-1 TPP. Added solute 0.2. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 2 × 10^-1 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 3,4,4,5-Tetramethylpyrazole + ¹O₂^* ®
Solvent: CCl₄

k/k_reference = 3.8
T = 253K

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine; meas. k/k_ref = 3.8; with 10^-6 mol L^-1 TPP. Added solute 0.2. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 2 × 10^-1 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 1,4-Diphenyl-1,3-butadiene + ¹O₂^* ®
Solvent: CCl₄

k/k_reference = 2.9 × 10^-1
T = 273K

Experimental method: Photolysis
Analytical method: VPC
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine. meas. k/k_ref = 0.29. Added solute 0.025. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 2.5 × 10^-2 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 3,4,4,5-Tetramethylpyrazole + ¹O₂^* ®
Solvent: CDCl₃

k/k_reference = 3.2
T = 253K

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine; meas. k/k_ref = 3.2. Added solute 0.2. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 2 × 10^-1 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 1,4-Diphenyl-1,3-butadiene + ¹O₂^* ®
Solvent: CDCl₃

k/k_reference = 3.0 × 10^-1
T = 253K

Experimental method: Photolysis
Analytical method: VPC
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 0.30. Added solute 0.1. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 1 × 10^-1 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 1,4-Diphenyl-1,3-butadiene + ¹O₂^* ®
Solvent: CDCl₃

k/k_reference = 2.2 × 10^-1
T = 253K

Experimental method: Photolysis
Analytical method: VPC
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine; meas. k/k_ref = 0.22. Added solute 0.1. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 1 × 10^-1 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 1,4-Diphenyl-1,3-butadiene + ¹O₂^* ®
Solvent: CDCl₃

k/k_reference = 2.8 × 10^-1
T = 253K

Experimental method: Photolysis
Analytical method: VPC
Data type: Relative value measured by steady state method

Photosensitizer = Poly-RB; meas. k/k_ref = 0.28. Added solute 0.1. [Indicator] = 1 × 10^-1 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 3,4,4,5-Tetramethylpyrazole + ¹O₂^* ®
Solvent: CH₂Cl₂

k/k_reference = 3.3
T = 253K

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine; meas. k/k_ref = 3.3. Added solute 0.2. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 2 × 10^-1 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 3,4,4,5-Tetramethylpyrazole + ¹O₂^* ®
Solvent: CHCl₃

k/k_reference = 3.0
T = 253K

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine; meas. k/k_ref = 3.0. Added solute 0.2. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 2 × 10^-1 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 3,4,4,5-Tetramethylpyrazole + ¹O₂^* ®
Solvent: CHCl₃

k/k_reference = 3.8
T = 253K

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = Methylene Blue; meas. k/k_ref = 3.8. Added solute 0.2. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 2 × 10^-1 (mol L^-1).

Landis, M.E.; Madoux, D.C.
J. Am. Chem. Soc. 101, 5106-5107 (1979)

Reaction: Acetone azine + ¹O₂^* ® products
Reference Reaction: 1,4-Diphenyl-1,3-butadiene + ¹O₂^* ®
Solvent: C₆F₆

k/k_reference = 2.8 × 10^-1
T = 273K

Experimental method: Photolysis
Analytical method: VPC
Data type: Relative value measured by steady state method

Photosensitizer = 5,10,15,20-Tetraphenylporphine; meas. k/k_ref = 0.28. Added solute 0.025. [Sensitizer] = 1 × 10^-4 (mol L^-1). [Indicator] = 2.5 × 10^-2 (mol L^-1).