O,N,N-Triethylhydroxylamine Singlet oxygen

Encinas, M.V.; Lemp, E.; Lissi, E.A.
J. Chem. Soc., Perkin Trans. 2, 1125-1127 (1987)

Reaction: O,N,N-Triethylhydroxylamine + ¹O₂^* ® products and/or physical quenching
Solvent: n-C₆H₁₄

k = 6.0 × 10⁵(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Excitation wavelength: 527 nm

Photosensitizer = Indicator = Rubrene; k_d not given.

Encinas, M.V.; Lemp, E.; Lissi, E.A.
J. Chem. Soc., Perkin Trans. 2, 1125-1127 (1987)

Reaction: O,N,N-Triethylhydroxylamine + ¹O₂^* ® products and/or physical quenching
Solvent: CH₃CN

k = 2.1 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator
Excitation wavelength: 527 nm

Photosensitizer = Rose Bengal dianion; Indicator = 9,10-Dimethylanthracene; used solvent k_d = 3.3 × 10⁴ s^-1.