Hydroxide-d ion Singlet oxygen

Rodgers, M.A.J.; Shand, M.A.
AFWL-TR-89-07, 1989, 24p.; AD-A211545

Reaction: OD^- + ¹O₂^* ® products and/or physical quenching
Solvent: D₂O

k = 5.5 × 10³(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Pyrenetetrasulfonate ion; soln. contg. 0.5-6 mol L^-1 NaOD. Added solute 1-6.