Oxygen Singlet oxygen

Afshari, E.; Schmidt, R.
Chem. Phys. Lett. 184, 128-132 (1991)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Solvent: Perfluorodecalin

k = 4.1 × 10³(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly
Excitation wavelength: 365 nm

Photosensitizer = Phenalen-1-one.

Afshari, E.; Schmidt, R.
Chem. Phys. Lett. 184, 128-132 (1991)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Solvent: Perfluorohexane

k = 2.6 × 10³(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly
Excitation wavelength: 365 nm

Photosensitizer = Phenalen-1-one.

Afshari, E.; Schmidt, R.
Chem. Phys. Lett. 184, 128-132 (1991)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Solvent: Tetrachloromethane

k = 3.9 × 10³(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly
Excitation wavelength: 365 nm

Photosensitizer = Phenalen-1-one.

Afshari, E.; Schmidt, R.
Chem. Phys. Lett. 184, 128-132 (1991)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Solvent: Freon 113

k = 3.2 × 10³(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly
Excitation wavelength: 365 nm

Photosensitizer = Phenalen-1-one.

Stevens, B.; Marsh, K.L.
J. Phys. Chem. 86, 4473-4476 (1982)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Solvent: CS₂

k = 1.3 × 10⁴(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Perylene.

Stevens, B.; Marsh, K.L.
J. Phys. Chem. 86, 4473-4476 (1982)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Solvent: Freon 113

k = 920(L mol^-1 s^-1), T = 298K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Photosensitizer = Perylene.

Klingshirn, H.; Faltermeier, B.; Hengl, W.; Maier, M.
Chem. Phys. Lett. 93, 485-489 (1982)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Solvent: O₂

k = 590(L mol^-1 s^-1), T = 77K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Liquid oxygen, direct laser excitation.

Protz, R.; Maier, M.
J. Chem. Phys. 73, 5464-5467 (1980)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Solvent: O₂

k = 600(L mol^-1 s^-1), T = 77K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Liquid oxygen, direct laser excitation, 1064 nm.

Matheson, I.B.C.; Lightner, D.A.
Photochem. Photobiol. 29, 933-935 (1979)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Reference Reaction: DPBF + ¹O₂^* ®
Solvent: CCl₂FCClF₂

k = 2.5 × 10³(L mol^-1 s^-1), T = 293K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly using indicator
Excitation wavelength: ? nm

Indicator = 1,3-Diphenylisobenzofuran; high pressure O₂.

Matheson, I.B.C.; Lee, J.; Yamanashi, B.S.; Wolbarsht, M.L.
J. Am. Chem. Soc. 96, 3343-3348 (1974)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Reference Reaction: DPBF + ¹O₂^* ®
Solvent: CCl₂FCClF₂

k = 2.7 × 10³(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly using indicator

Indicator = 1,3-Diphenylisobenzofuran; high pressure O₂.

Huestis, D.L.; Black, G.; Edelstein, S.A.; Sharpless, R.L.
J. Chem. Phys. 60, 4471-4474 (1974)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Solvent: O₂

k = 600(L mol^-1 s^-1), T = 77K

Experimental method: Flash photolysis
Analytical method: infrared luminescence
Data type: Absolute value measured directly

Liquid oxygen, direct laser excitation, 1060 nm; k = 1.3 × 10³ (T/300)^0.5 [71FIN/SNE].

Stevens, B.
Acc. Chem. Res. 6, 90-96 (1973)

Reaction: O₂ + ¹O₂^* ® products and/or physical quenching
Reference Reaction: 9,10-Dimethylanthracene + ¹O₂^* ®
Solvent: C₆H₆

k ~ 6 × 10⁴(L mol^-1 s^-1)

Experimental method: Photolysis
Data type: Absolute value measured directly using indicator

Photosensitizer = 9,10-Dimethylanthracene; Reported as unpublished data.