p-(Dimethylamino)thioanisole Singlet oxygen

Inoue, K.; Matsuura, T.; Saito, I.
Tetrahedron 41, 2177-2181 (1985)

Reaction: 4-CH₃SC₆H₄N(CH₃)₂ + ¹O₂^* ® products and/or physical quenching
Solvent: Benzene

k = 3.0 × 10⁷(L mol^-1 s^-1), T = 308K

Experimental method: Chemical reaction
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = 1,3-Diphenylisobenzofuran; used solvent k_d = 5.4 × 10⁴ s^-1; ¹O₂* from MNPO₂.

Inoue, K.; Matsuura, T.; Saito, I.
Tetrahedron 41, 2177-2181 (1985)

Reaction: 4-CH₃SC₆H₄N(CH₃)₂ + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH, 50%, H₂O, 50%

k = 3.6 × 10⁸(L mol^-1 s^-1), T = 308K

Experimental method: Chemical reaction
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Indicator = 1,3-Diphenylisobenzofuran; used solvent k_d = 2.8 × 10⁵ s^-1; ¹O₂* from MNPO₂.