Hexamethylenedithiocarbamate Singlet oxygen

Yamase, T.; Kokado, H.; Inoue, E.
Bull. Chem. Soc. Jpn. 45, 726-731 (1972)

Reaction: Hexamethylenedithiocarbamate + ¹O₂^* ® products and/or physical quenching
Solvent: EtOH

k = 1.5 × 10⁸(L mol^-1 s^-1), solvent k_d = 1.0 × 10⁴(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: oxygen consumption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Rose Bengal dianion; Indicator = b-Carotene; k for indicator = 5.0 × 10⁹ L/(mol·s);