Dibutyl sulfide Singlet oxygen

Xu, D.; Xu, B.; Cui, G.; Wu, S.
Huaxue Tongbao, 17-19 (1985)

Reaction: Dibutyl sulfide + ¹O₂^* ® products and/or physical quenching
Solvent: Methanol

k = 2.5 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Data type: Derived from steady state measurements using indicator

Photosensitizer = Rose Bengal dianion; used solvent k_d = 1.8 × 10⁵ s^-1; Indicator = 1,3-Diphenylisobenzofuran.

Monroe, B.M.
Photochem. Photobiol. 29, 761-764 (1979)

Reaction: Dibutyl sulfide + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 2.3 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).

Martin, R.L.
Ph.D., Thesis, Georgetown Univ., Wash. D.C., 1972, 330p.

Reaction: Dibutyl sulfide + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 8.2 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements using indicator

Photosensitizer = Methylene Blue; Indicator = 1,3-Diphenylisobenzofuran; used solvent k_d = 9.0 × 10⁴ s^-1.