4,6,6-Trimethylbicyclo[3.1.1]hept-3-ene-2-thione Singlet oxygen

Pushkara Rao, V.; Ramamurthy, V.
Tetrahedron 41, 2169-2176 (1985)

Reaction: 4,6,6-Trimethylbicyclo[3.1.1]hept-3-ene-2-thione + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 5.6 × 10⁵(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).