Bicyclo[2.2.1]heptane-2-thione Singlet oxygen

Ramnath, N.; Jayathertha Rao, V.; Ramesh, V.; Ramamurthy, V.
Chem. Lett., 89-92 (1982)

Reaction: Bicyclo[2.2.1]heptane-2-thione + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 1.8 × 10⁵(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s); see also [83RAM/RAM].