Diphenyl sulfide Singlet oxygen

Ando, W.; Kabe, Y.; Miyazaki, H.
Photochem. Photobiol. 31, 191-194 (1980)

Reaction: (C₆H₅)₂S + ¹O₂^* ® products
Reference Reaction: 1-Chloro-4-(phenylthio)benzene + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 1.1

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; meas. k/k_ref = 1.1.

Ando, W.; Kabe, Y.; Miyazaki, H.
Photochem. Photobiol. 31, 191-194 (1980)

Reaction: (C₆H₅)₂S + ¹O₂^* ® products
Reference Reaction: 1-Methoxy-4-(phenylthio)benzene + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 4.1 × 10^-1

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; meas. k/k_ref = 0.41.

Ando, W.; Kabe, Y.; Miyazaki, H.
Photochem. Photobiol. 31, 191-194 (1980)

Reaction: (C₆H₅)₂S + ¹O₂^* ® products
Reference Reaction: 1-Methyl-4-(phenylthio)benzene + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 5.4 × 10^-1

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; meas. k/k_ref = 0.54.

Ando, W.; Kabe, Y.; Miyazaki, H.
Photochem. Photobiol. 31, 191-194 (1980)

Reaction: (C₆H₅)₂S + ¹O₂^* ® products
Reference Reaction: 1-Nitro-4-(phenylthio)benzene + ¹O₂^* ®
Solvent: MeOH

k/k_reference = 3.3

Experimental method: Photolysis
Analytical method: gas chromatography
Data type: Relative value measured by steady state method

Photosensitizer = Rose Bengal dianion; meas. k/k_ref = 3.3.

Monroe, B.M.
Photochem. Photobiol. 29, 761-764 (1979)

Reaction: (C₆H₅)₂S + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 8.0 × 10⁴(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).

Kacher, M.L.; Foote, C.S.
Photochem. Photobiol. 29, 765-769 (1979)

Reaction: (C₆H₅)₂S + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k ~1.0 × 10⁵(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements using indicator

Photosensitizer = Rose Bengal dianion; Indicator = 2,5-Diphenylfuran; used solvent k_d = 1.1 × 10⁵ s^-1.