4-Chlorophenyl methyl sulfide Singlet oxygen

Monroe, B.M.
Photochem. Photobiol. 29, 761-764 (1979)

Reaction: 4-Chlorophenyl methyl sulfide + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 1.0 × 10⁶(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; k for indicator = 5.3 × 10⁷ L/(mol·s); used solvent k_d = 1.7 × 10⁴ s^-1.

Kacher, M.L.; Foote, C.S.
Photochem. Photobiol. 29, 765-769 (1979)

Reaction: 4-Chlorophenyl methyl sulfide + ¹O₂^* ® products and/or physical quenching
Solvent: MeOH

k = 8.3 × 10⁵(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV emission
Data type: Derived from steady state measurements using indicator

Photosensitizer = Rose Bengal dianion; Indicator = 2,5-Diphenylfuran; used solvent k_d = 1.1 × 10⁵ s^-1.