Bis[hydrotris(1-pyrazolyl)borato]nickel(II) Singlet oxygen

Monroe, B.M.; Mrowca, J.J.
J. Phys. Chem. 83, 591-595 (1979)

Reaction: Bis[hydrotris(1-pyrazolyl)borato]nickel(II) + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 2.1 × 10⁶(L mol^-1 s^-1)

Experimental method: Modulated photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).