Bis(O,O'-diphenylphosphorodithiolato)nickel(II) Singlet oxygen

Monroe, B.M.; Mrowca, J.J.
J. Phys. Chem. 83, 591-595 (1979)

Reaction: Nickel(II) bis(O,O'-diphenyldithiophosphate) + ¹O₂^* ® products and/or physical quenching
Solvent: CHCl₃

k = 1.1 × 10¹⁰(L mol^-1 s^-1)

Experimental method: Modulated photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 1.7 × 10⁴ s^-1; k for indicator = 5.3 × 10⁷ L/(mol·s).

Edilashvili, I.L.; Ioseliani, K.B.; Dzhanibekov, N.F.; Markova, E.I.; Akhmed-zade, D.A.
Russ. J. Phys. Chem. 52, 1197-1198 (1978)

Reaction: Nickel(II) bis(O,O'-diphenyldithiophosphate) + ¹O₂^* ® products and/or physical quenching
Solvent: C₆H₆

k = 2.5 × 10⁹(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: vis-UV absorption
Data type: Derived from steady state measurements using indicator

Photosensitizer = Indicator = Rubrene; used solvent k_d = 2.8 × 10⁴ s^-1; k for indicator = 3 × 10⁷ L/(mol·s).